XPS investigations of tribolayers formed on TiN and (Ti,Re)N coatings

Serkan Oktay; Zafer Kahraman; Mustafa Urgen; Kursat Kazmanli

doi:10.1016/j.apsusc.2014.12.023

XPS investigations of tribolayers formed on TiN and (Ti,Re)N coatings

Serkan Oktay
, Zafer Kahraman
, Mustafa Urgen
, Kursat Kazmanli^*

^*Bu çalışma için yazışmadan sorumlu yazar

Metalurji ve Malzeme Müh.Böl.

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

131 Atıf (Scopus)

Özet

TiN and (Ti,Re)N coatings were deposited on high-speed-steel substrates by a hybrid coating system composed of cathodic arc PVD and magnetron sputtering techniques. In order to keep rhenium content low (8 ± 1.9 at.%) in the coating, magnetron sputtering technique was utilized to evaporate rhenium. The (Ti,Re)N coating consisted of TiN and ReN _x (x > 1.33) phases. The hardness of TiN and (Ti,Re)N were 31 GPa and 29 GPa (± 2 GPa), respectively. Tribological behaviors of the samples were tested against Al ₂ O ₃ balls at 21°C (RT) and 150°C (HT) by reciprocating wear technique. The tribolayers were analyzed by XPS technique. Friction coefficients of TiN were 0.56, 0.35 for 21°C and 150°C tests, respectively. Rhenium addition to TiN drastically dropped the friction coefficients to 0.22 and 0.17 for RT and HT samples. Rhenium addition also improved the wear resistance of the coating at both test temperatures. For TiN, main oxide component of the tribolayers was Ti ₂ O ₃ for RT tests and TiO ₂ for HT tests. The oxide layer formed on (Ti,Re)N were the mixture of TiO ₂ , TiON, ReO ₂ and Re ₂ O ₇ for both test temperatures. Re ₂ O ₇ provided very low friction coefficient to (Ti,Re)N. The findings are consistent with the crystal chemistry approach.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	255-261
Sayfa sayısı	7
Dergi	Applied Surface Science
Hacim	328
DOI'lar	https://doi.org/10.1016/j.apsusc.2014.12.023
Yayın durumu	Yayınlandı - 15 Şub 2015

Bibliyografik not

Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.

Finansman

A part of this study was supported by The Scientific and Technological Research Council of Turkey (TUBITAK, project #105M146). The authors gratefully thank Prof. Dr. Gültekin Göller, Hüseyin Sezer and Berk Alkan for their technical supports in SEM and XPS investigations.

Finansörler	Finansör numarası
TUBITAK	105M146
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

Belgeye Erişim

10.1016/j.apsusc.2014.12.023

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{e39024d42d9e47ec91e2c282c4b3d1e3,

title = "XPS investigations of tribolayers formed on TiN and (Ti,Re)N coatings",

abstract = " TiN and (Ti,Re)N coatings were deposited on high-speed-steel substrates by a hybrid coating system composed of cathodic arc PVD and magnetron sputtering techniques. In order to keep rhenium content low (8 ± 1.9 at.\%) in the coating, magnetron sputtering technique was utilized to evaporate rhenium. The (Ti,Re)N coating consisted of TiN and ReN x (x > 1.33) phases. The hardness of TiN and (Ti,Re)N were 31 GPa and 29 GPa (± 2 GPa), respectively. Tribological behaviors of the samples were tested against Al 2 O 3 balls at 21°C (RT) and 150°C (HT) by reciprocating wear technique. The tribolayers were analyzed by XPS technique. Friction coefficients of TiN were 0.56, 0.35 for 21°C and 150°C tests, respectively. Rhenium addition to TiN drastically dropped the friction coefficients to 0.22 and 0.17 for RT and HT samples. Rhenium addition also improved the wear resistance of the coating at both test temperatures. For TiN, main oxide component of the tribolayers was Ti 2 O 3 for RT tests and TiO 2 for HT tests. The oxide layer formed on (Ti,Re)N were the mixture of TiO 2 , TiON, ReO 2 and Re 2 O 7 for both test temperatures. Re 2 O 7 provided very low friction coefficient to (Ti,Re)N. The findings are consistent with the crystal chemistry approach.",

keywords = "Crystal chemistry approach, PVD coatings, Rhenium nitride, Titanium nitride, Tribology, XPS investigation",

author = "Serkan Oktay and Zafer Kahraman and Mustafa Urgen and Kursat Kazmanli",

year = "2015",

month = feb,

day = "15",

doi = "10.1016/j.apsusc.2014.12.023",

language = "English",

volume = "328",

pages = "255--261",

journal = "Applied Surface Science",

issn = "0169-4332",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - XPS investigations of tribolayers formed on TiN and (Ti,Re)N coatings

AU - Oktay, Serkan

AU - Kahraman, Zafer

AU - Urgen, Mustafa

AU - Kazmanli, Kursat

PY - 2015/2/15

Y1 - 2015/2/15

N2 - TiN and (Ti,Re)N coatings were deposited on high-speed-steel substrates by a hybrid coating system composed of cathodic arc PVD and magnetron sputtering techniques. In order to keep rhenium content low (8 ± 1.9 at.%) in the coating, magnetron sputtering technique was utilized to evaporate rhenium. The (Ti,Re)N coating consisted of TiN and ReN x (x > 1.33) phases. The hardness of TiN and (Ti,Re)N were 31 GPa and 29 GPa (± 2 GPa), respectively. Tribological behaviors of the samples were tested against Al 2 O 3 balls at 21°C (RT) and 150°C (HT) by reciprocating wear technique. The tribolayers were analyzed by XPS technique. Friction coefficients of TiN were 0.56, 0.35 for 21°C and 150°C tests, respectively. Rhenium addition to TiN drastically dropped the friction coefficients to 0.22 and 0.17 for RT and HT samples. Rhenium addition also improved the wear resistance of the coating at both test temperatures. For TiN, main oxide component of the tribolayers was Ti 2 O 3 for RT tests and TiO 2 for HT tests. The oxide layer formed on (Ti,Re)N were the mixture of TiO 2 , TiON, ReO 2 and Re 2 O 7 for both test temperatures. Re 2 O 7 provided very low friction coefficient to (Ti,Re)N. The findings are consistent with the crystal chemistry approach.

AB - TiN and (Ti,Re)N coatings were deposited on high-speed-steel substrates by a hybrid coating system composed of cathodic arc PVD and magnetron sputtering techniques. In order to keep rhenium content low (8 ± 1.9 at.%) in the coating, magnetron sputtering technique was utilized to evaporate rhenium. The (Ti,Re)N coating consisted of TiN and ReN x (x > 1.33) phases. The hardness of TiN and (Ti,Re)N were 31 GPa and 29 GPa (± 2 GPa), respectively. Tribological behaviors of the samples were tested against Al 2 O 3 balls at 21°C (RT) and 150°C (HT) by reciprocating wear technique. The tribolayers were analyzed by XPS technique. Friction coefficients of TiN were 0.56, 0.35 for 21°C and 150°C tests, respectively. Rhenium addition to TiN drastically dropped the friction coefficients to 0.22 and 0.17 for RT and HT samples. Rhenium addition also improved the wear resistance of the coating at both test temperatures. For TiN, main oxide component of the tribolayers was Ti 2 O 3 for RT tests and TiO 2 for HT tests. The oxide layer formed on (Ti,Re)N were the mixture of TiO 2 , TiON, ReO 2 and Re 2 O 7 for both test temperatures. Re 2 O 7 provided very low friction coefficient to (Ti,Re)N. The findings are consistent with the crystal chemistry approach.

KW - Crystal chemistry approach

KW - PVD coatings

KW - Rhenium nitride

KW - Titanium nitride

KW - Tribology

KW - XPS investigation

UR - https://www.scopus.com/pages/publications/84922240555

U2 - 10.1016/j.apsusc.2014.12.023

DO - 10.1016/j.apsusc.2014.12.023

M3 - Article

AN - SCOPUS:84922240555

SN - 0169-4332

VL - 328

SP - 255

EP - 261

JO - Applied Surface Science

JF - Applied Surface Science

ER -

XPS investigations of tribolayers formed on TiN and (Ti,Re)N coatings

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

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