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Use of cyclodextrin and calcium chloride for enhanced removal of mercury from soil

  • Xiaojiang Wang
  • , Irfan Yolcubal
  • , Weizi Wang
  • , Janick Artiola
  • , Raina Maier
  • , Mark Brusseau*
  • *Bu çalışma için yazışmadan sorumlu yazar
  • University of Arizona
  • Kocaeli University

Araştırma çıktısı: Dergi yayınıMakaleHakem

11 Atıf (Scopus)

Özet

The use of solutions containing carboxymethyl-β-cyclodextrin (CMCD) or CaCl2 for enhancing the removal of Hg from a sandy soil was investigated using batch and column experiments. The retention of Hg appeared to be controlled by specific adsorption reactions, which greatly constrained Hg removal when using water (KNO3 solution) to flush columns packed with contaminated soil. The results showed that the two reagents did enhance the removal of Hg from the soil. For example, 81% and 60% of Hg was recovered after 50 pore volumes of flushing with 50 mM CaCl2 and 2 mM CMCD, respectively, compared to 24% recovery for a 10 mM KNO3 solution. However, significant tailing and delayed recovery of Hg during the elution process occurred in the presence of all reagents, indicating that the removal of Hg from the soil was rate limited.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)1888-1892
Sayfa sayısı5
DergiEnvironmental Toxicology and Chemistry
Hacim23
Basın numarası8
DOI'lar
Yayın durumuYayınlandı - Ağu 2004
Harici olarak yayınlandıEvet

Finansman

FinansörlerFinansör numarası
National Institute of Environmental Health SciencesP42ES004940

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