Thienothiophene and Triphenylbenzene Based Electroactive Conjugated Porous Polymer for Oxygen Reduction Reaction (ORR)

Recep Isci; Timuçin Balkan; Saeede Tafazoli; Berkay Sütay; Mehmet S. Eroglu; Turan Ozturk

doi:10.1021/acsaem.2c01830

Thienothiophene and Triphenylbenzene Based Electroactive Conjugated Porous Polymer for Oxygen Reduction Reaction (ORR)

Recep Isci
, Timuçin Balkan
, Saeede Tafazoli
, Berkay Sütay
, Mehmet S. Eroglu
, Turan Ozturk^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Koc University
Marmara University
Scientific and Technological Research Council of Turkey

Araştırma çıktısı: Dergi yayını › Makale › Hakem

37 Atıf (Scopus)

Özet

Catalysts based on metal-free conjugated porous polymers (CPPs) are still rare for electrochemical oxygen reduction reactions (ORR). In this study, a conjugated porous polymer, TT-TPB, based on thieno[3,2-b]thiophene (TT) and triphenylbenzene (TPB), was synthesized applying palladium(0) catalyzed Suzuki coupling reaction and its ORR activity was investigated in alkaline condition. It demonstrated comparable electrocatalytic performance of ≈0.89-0.9 V E_onsetvs RHE with the commercially available Pt/C. Density-functional theory (DFT) calculations revealed that TT-TPB featured efficient electrocatalytic active sites derived from volumetric, areal, and O₂adsorbing calculations, which were in line with the experimental results. Moreover, semiconducting and surface properties of TT-TPB were investigated in detail using electrochemical and spectrophotometric techniques. This work shows the potential application of thienothiophene-based metal-free CPP in the electrochemical conversion process.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	13284-13292
Sayfa sayısı	9
Dergi	ACS Applied Energy Materials
Hacim	5
Basın numarası	11
DOI'lar	https://doi.org/10.1021/acsaem.2c01830
Yayın durumu	Yayınlandı - 28 Kas 2022

Bibliyografik not

Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.

Finansman

We thank Higher Education Council of Turkey (YOK) and TUBITAK grants to R.I. (PhD, 100/2000 YOK and 2211A BIDEP/TUBITAK). The authors thank ITU (Istanbul Technical University) and Unsped Global Lojistik, Turkey, for financial support. We also thank Dr. Sarp Kaya and KUTEM (Koç University Tüpraş Energy Center) for using their infrastructure. T.B. also thanks Kaan Şimşek for his valuable help.

Finansörler
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1021/acsaem.2c01830

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{234c9f0279fa4906a4a54bc718848e36,

title = "Thienothiophene and Triphenylbenzene Based Electroactive Conjugated Porous Polymer for Oxygen Reduction Reaction (ORR)",

abstract = "Catalysts based on metal-free conjugated porous polymers (CPPs) are still rare for electrochemical oxygen reduction reactions (ORR). In this study, a conjugated porous polymer, TT-TPB, based on thieno[3,2-b]thiophene (TT) and triphenylbenzene (TPB), was synthesized applying palladium(0) catalyzed Suzuki coupling reaction and its ORR activity was investigated in alkaline condition. It demonstrated comparable electrocatalytic performance of ≈0.89-0.9 V Eonsetvs RHE with the commercially available Pt/C. Density-functional theory (DFT) calculations revealed that TT-TPB featured efficient electrocatalytic active sites derived from volumetric, areal, and O2adsorbing calculations, which were in line with the experimental results. Moreover, semiconducting and surface properties of TT-TPB were investigated in detail using electrochemical and spectrophotometric techniques. This work shows the potential application of thienothiophene-based metal-free CPP in the electrochemical conversion process.",

keywords = "catalyst kinetics, conjugated porous polymer (CPP), metal-free electrocatalyst, oxygen reduction reaction (ORR), polymeric electrocatalyst, thienothiophene",

author = "Recep Isci and Timu{\c c}in Balkan and Saeede Tafazoli and Berkay S{\"u}tay and Eroglu, \{Mehmet S.\} and Turan Ozturk",

year = "2022",

month = nov,

day = "28",

doi = "10.1021/acsaem.2c01830",

language = "English",

volume = "5",

pages = "13284--13292",

journal = "ACS Applied Energy Materials",

issn = "2574-0962",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Thienothiophene and Triphenylbenzene Based Electroactive Conjugated Porous Polymer for Oxygen Reduction Reaction (ORR)

AU - Isci, Recep

AU - Balkan, Timuçin

AU - Tafazoli, Saeede

AU - Sütay, Berkay

AU - Eroglu, Mehmet S.

AU - Ozturk, Turan

PY - 2022/11/28

Y1 - 2022/11/28

N2 - Catalysts based on metal-free conjugated porous polymers (CPPs) are still rare for electrochemical oxygen reduction reactions (ORR). In this study, a conjugated porous polymer, TT-TPB, based on thieno[3,2-b]thiophene (TT) and triphenylbenzene (TPB), was synthesized applying palladium(0) catalyzed Suzuki coupling reaction and its ORR activity was investigated in alkaline condition. It demonstrated comparable electrocatalytic performance of ≈0.89-0.9 V Eonsetvs RHE with the commercially available Pt/C. Density-functional theory (DFT) calculations revealed that TT-TPB featured efficient electrocatalytic active sites derived from volumetric, areal, and O2adsorbing calculations, which were in line with the experimental results. Moreover, semiconducting and surface properties of TT-TPB were investigated in detail using electrochemical and spectrophotometric techniques. This work shows the potential application of thienothiophene-based metal-free CPP in the electrochemical conversion process.

AB - Catalysts based on metal-free conjugated porous polymers (CPPs) are still rare for electrochemical oxygen reduction reactions (ORR). In this study, a conjugated porous polymer, TT-TPB, based on thieno[3,2-b]thiophene (TT) and triphenylbenzene (TPB), was synthesized applying palladium(0) catalyzed Suzuki coupling reaction and its ORR activity was investigated in alkaline condition. It demonstrated comparable electrocatalytic performance of ≈0.89-0.9 V Eonsetvs RHE with the commercially available Pt/C. Density-functional theory (DFT) calculations revealed that TT-TPB featured efficient electrocatalytic active sites derived from volumetric, areal, and O2adsorbing calculations, which were in line with the experimental results. Moreover, semiconducting and surface properties of TT-TPB were investigated in detail using electrochemical and spectrophotometric techniques. This work shows the potential application of thienothiophene-based metal-free CPP in the electrochemical conversion process.

KW - catalyst kinetics

KW - conjugated porous polymer (CPP)

KW - metal-free electrocatalyst

KW - oxygen reduction reaction (ORR)

KW - polymeric electrocatalyst

KW - thienothiophene

UR - https://www.scopus.com/pages/publications/85141491965

U2 - 10.1021/acsaem.2c01830

DO - 10.1021/acsaem.2c01830

M3 - Article

AN - SCOPUS:85141491965

SN - 2574-0962

VL - 5

SP - 13284

EP - 13292

JO - ACS Applied Energy Materials

JF - ACS Applied Energy Materials

IS - 11

ER -

Thienothiophene and Triphenylbenzene Based Electroactive Conjugated Porous Polymer for Oxygen Reduction Reaction (ORR)

Özet

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