Thieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cells

Recep Isci; Melis Unal; Tamer Yesil; Alper Ekici; Berkay Sütay; Ceylan Zafer; Turan Ozturk

doi:10.3389/fmats.2023.1125462

Thieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cells

Recep Isci, Melis Unal, Tamer Yesil, Alper Ekici, Berkay Sütay, Ceylan Zafer^*, Turan Ozturk^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

16 Atıf (Scopus)

Özet

Heterocyclic compounds have played significant roles in achieving high performance as hole transport materials (HTMs) for perovskite solar cell (PSC) applications. Various studies have focused on the development of fused heterocyclic conjugated structures for hole transport materials. In this report, three novel π-extended conjugated materials (M1-M3), based on thieno[3,2-b]thiophene (TT) and 4,4′-dimethoxytriphenylamine [TPA(OMe)₂], were designed and successfully synthesized via Palladium (0) catalyzed Suzuki coupling reaction. Their optical, electrochemical, and thermal properties were investigated by UV-Vis, fluorescence, cyclic voltammetry, and thermal analysis. The materials were utilized as hole transport materials in p-i-n architecture perovskite solar cells, which displayed performances of open-circuit voltage (V_oc) as high as 1,050 mV, a maximum short-circuit current (J_sc) of 16,9 mA/cm², a maximum fill factor (FF) of 29.3%, and a power conversion efficiency (PCE) of 5.20%. This work demonstrated that thieno[3,2-b]thiophene and TPA(OMe)₂-based structures are promising cores for high-performance hole transport materials in perovskite solar cell architecture.

Orijinal dil	İngilizce
Makale numarası	1125462
Dergi	Frontiers in Materials
Hacim	10
DOI'lar	https://doi.org/10.3389/fmats.2023.1125462
Yayın durumu	Yayınlandı - 2023

Bibliyografik not

Publisher Copyright:
Copyright © 2023 Isci, Unal, Yesil, Ekici, Sütay, Zafer and Ozturk.

Finansman

We thank the Higher Education Council of Türkiye (YOK) and TUBITAK grants to RI (PhD., 100/2000 YOK and 2211A BIDEP/TUBITAK); ITU (Istanbul Technical University), 122Z568 numbered TUBITAK 1001 Project; TY within the Program nr: 2211/C (Grant nr: 1649B032100473); and Unsped Global Lojistik, Türkiye, for the financial support. The computing resources used in this work were provided by the National Center for High-Performance Computing (UHeM) under grant number 1010722021.

Finansörler	Finansör numarası
Higher Education Council of Türkiye	2211A BIDEP/TUBITAK, 100/2000 YOK
Ulusal Yüksek Başarımlı Hesaplama Merkezi, Istanbul Teknik Üniversitesi	1010722021
Istanbul Teknik Üniversitesi	122Z568, 1649B032100473
Sheikh Bahaei National High Performance Computing Center, Isfahan University of Technology

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

Belgeye Erişim

10.3389/fmats.2023.1125462

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Thieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cells",

abstract = "Heterocyclic compounds have played significant roles in achieving high performance as hole transport materials (HTMs) for perovskite solar cell (PSC) applications. Various studies have focused on the development of fused heterocyclic conjugated structures for hole transport materials. In this report, three novel π-extended conjugated materials (M1-M3), based on thieno[3,2-b]thiophene (TT) and 4,4′-dimethoxytriphenylamine [TPA(OMe)2], were designed and successfully synthesized via Palladium (0) catalyzed Suzuki coupling reaction. Their optical, electrochemical, and thermal properties were investigated by UV-Vis, fluorescence, cyclic voltammetry, and thermal analysis. The materials were utilized as hole transport materials in p-i-n architecture perovskite solar cells, which displayed performances of open-circuit voltage (Voc) as high as 1,050 mV, a maximum short-circuit current (Jsc) of 16,9 mA/cm2, a maximum fill factor (FF) of 29.3%, and a power conversion efficiency (PCE) of 5.20%. This work demonstrated that thieno[3,2-b]thiophene and TPA(OMe)2-based structures are promising cores for high-performance hole transport materials in perovskite solar cell architecture.",

keywords = "hole transport materials, perovskite solar cell, solution processable, thieno[3,2-b]thiophene, triphenylamine",

author = "Recep Isci and Melis Unal and Tamer Yesil and Alper Ekici and Berkay S{\"u}tay and Ceylan Zafer and Turan Ozturk",

note = "Publisher Copyright: Copyright {\textcopyright} 2023 Isci, Unal, Yesil, Ekici, S{\"u}tay, Zafer and Ozturk.",

year = "2023",

doi = "10.3389/fmats.2023.1125462",

language = "English",

volume = "10",

journal = "Frontiers in Materials",

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T1 - Thieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cells

AU - Isci, Recep

AU - Unal, Melis

AU - Yesil, Tamer

AU - Ekici, Alper

AU - Sütay, Berkay

AU - Zafer, Ceylan

AU - Ozturk, Turan

PY - 2023

Y1 - 2023

N2 - Heterocyclic compounds have played significant roles in achieving high performance as hole transport materials (HTMs) for perovskite solar cell (PSC) applications. Various studies have focused on the development of fused heterocyclic conjugated structures for hole transport materials. In this report, three novel π-extended conjugated materials (M1-M3), based on thieno[3,2-b]thiophene (TT) and 4,4′-dimethoxytriphenylamine [TPA(OMe)2], were designed and successfully synthesized via Palladium (0) catalyzed Suzuki coupling reaction. Their optical, electrochemical, and thermal properties were investigated by UV-Vis, fluorescence, cyclic voltammetry, and thermal analysis. The materials were utilized as hole transport materials in p-i-n architecture perovskite solar cells, which displayed performances of open-circuit voltage (Voc) as high as 1,050 mV, a maximum short-circuit current (Jsc) of 16,9 mA/cm2, a maximum fill factor (FF) of 29.3%, and a power conversion efficiency (PCE) of 5.20%. This work demonstrated that thieno[3,2-b]thiophene and TPA(OMe)2-based structures are promising cores for high-performance hole transport materials in perovskite solar cell architecture.

AB - Heterocyclic compounds have played significant roles in achieving high performance as hole transport materials (HTMs) for perovskite solar cell (PSC) applications. Various studies have focused on the development of fused heterocyclic conjugated structures for hole transport materials. In this report, three novel π-extended conjugated materials (M1-M3), based on thieno[3,2-b]thiophene (TT) and 4,4′-dimethoxytriphenylamine [TPA(OMe)2], were designed and successfully synthesized via Palladium (0) catalyzed Suzuki coupling reaction. Their optical, electrochemical, and thermal properties were investigated by UV-Vis, fluorescence, cyclic voltammetry, and thermal analysis. The materials were utilized as hole transport materials in p-i-n architecture perovskite solar cells, which displayed performances of open-circuit voltage (Voc) as high as 1,050 mV, a maximum short-circuit current (Jsc) of 16,9 mA/cm2, a maximum fill factor (FF) of 29.3%, and a power conversion efficiency (PCE) of 5.20%. This work demonstrated that thieno[3,2-b]thiophene and TPA(OMe)2-based structures are promising cores for high-performance hole transport materials in perovskite solar cell architecture.

KW - hole transport materials

KW - perovskite solar cell

KW - solution processable

KW - thieno[3,2-b]thiophene

KW - triphenylamine

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U2 - 10.3389/fmats.2023.1125462

DO - 10.3389/fmats.2023.1125462

M3 - Article

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JO - Frontiers in Materials

JF - Frontiers in Materials

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Thieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cells

Özet

Bibliyografik not

Finansman

BM SKH

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

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