Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Kubra Dogan Demir; Baris Kiskan; Binnur Aydogan; Yusuf Yagci

doi:10.1016/j.reactfunctpolym.2012.04.016

Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Kubra Dogan Demir, Baris Kiskan^*, Binnur Aydogan, Yusuf Yagci

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

97 Atıf (Scopus)

Özet

Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	346-359
Sayfa sayısı	14
Dergi	Reactive and Functional Polymers
Hacim	73
Basın numarası	2
DOI'lar	https://doi.org/10.1016/j.reactfunctpolym.2012.04.016
Yayın durumu	Yayınlandı - Şub 2013

Finansman

The authors thank to Istanbul Technical University Research Fund and TUBITAK (The Scientific and Technical Research Council of Turkey), Project No: 110T-723.

Finansörler	Finansör numarası
Istanbul Technical University Research Fund
TUBITAK
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	110T-723

Belgeye Erişim

10.1016/j.reactfunctpolym.2012.04.016

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{308fcec0bb784a33a2c7fbe38321470f,

title = "Thermally curable main-chain benzoxazine prepolymers via polycondensation route",

abstract = "Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.",

keywords = "Benzoxazine, Crosslinking, Polybenzoxazine, Polycondensation, Ring opening polymerization, Thermal curing, Thermosetting",

author = "Demir, {Kubra Dogan} and Baris Kiskan and Binnur Aydogan and Yusuf Yagci",

year = "2013",

month = feb,

doi = "10.1016/j.reactfunctpolym.2012.04.016",

language = "English",

volume = "73",

pages = "346--359",

journal = "Reactive and Functional Polymers",

issn = "1381-5148",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Thermally curable main-chain benzoxazine prepolymers via polycondensation route

AU - Demir, Kubra Dogan

AU - Kiskan, Baris

AU - Aydogan, Binnur

AU - Yagci, Yusuf

PY - 2013/2

Y1 - 2013/2

N2 - Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.

AB - Polybenzoxazines are addition-cure thermosetting polymers exhibiting versatility in a wide range of applications due to their good mechanical properties, dimensional stability, chemical resistivity, flame resistance property phenolic or epoxy resins have myriad applications in diverse fields starting from commodity materials to high technology aerospace industries. In this paper, we present synthetic strategies to incorporate thermally curable benzoxazine functionality into polymers as main-chain fashion in order to further improve various properties. The strategies successfully employed including monomer synthesis and polycondensation routes like Mannich reaction, click chemistry, hydrosilylations, and coupling reactions. The structure-property relationships of the cured materials have also been presented and discussed.

KW - Benzoxazine

KW - Crosslinking

KW - Polybenzoxazine

KW - Polycondensation

KW - Ring opening polymerization

KW - Thermal curing

KW - Thermosetting

UR - http://www.scopus.com/inward/record.url?scp=84872603651&partnerID=8YFLogxK

U2 - 10.1016/j.reactfunctpolym.2012.04.016

DO - 10.1016/j.reactfunctpolym.2012.04.016

M3 - Article

AN - SCOPUS:84872603651

SN - 1381-5148

VL - 73

SP - 346

EP - 359

JO - Reactive and Functional Polymers

JF - Reactive and Functional Polymers

IS - 2

ER -

Thermally curable main-chain benzoxazine prepolymers via polycondensation route

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap