The effect of cationic salt on photoinitiated free radical polymerization using polysilanes

Nergis Arsu; Gurkan Hizal; Yusuf Yagci

doi:10.1080/10601329508020347

The effect of cationic salt on photoinitiated free radical polymerization using polysilanes

Nergis Arsu, Gurkan Hizal, Yusuf Yagci

Yildiz Technical University

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

6 Atıf (Scopus)

Özet

Photoinitiated free radical polymerization of methylmethacrylate (MMA), (N-isopropyfcarbamate) ethylpropenoate (CL-960) and tripropyleneglycol diacrylate (TPGDA) by using polysilanes in the presence of N-ethoxy-2 methyl pyridinium bexafluorophosphate (EMP⁺PF₆) and diphenyliodontum hexaffurophosphate (Ph2l+ PF₆) was studied In the presence of the cationic salts the rate of photopolymerization was significantly increased The effect was attributed to the oxidation of silyl radicals formed from the photoscission of polysilane by pyndimum or diphenliodomum salts. The resulting radicals species are more capable of initiating the radical polymehzation.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1257-1262
Sayfa sayısı	6
Dergi	Journal of Macromolecular Science - Pure and Applied Chemistry
Hacim	32
Basın numarası	sup8
DOI'lar	https://doi.org/10.1080/10601329508020347
Yayın durumu	Yayınlandı - 1995
Harici olarak yayınlandı	Evet

Belgeye Erişim

10.1080/10601329508020347

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Alıntı Yap

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abstract = "Photoinitiated free radical polymerization of methylmethacrylate (MMA), (N-isopropyfcarbamate) ethylpropenoate (CL-960) and tripropyleneglycol diacrylate (TPGDA) by using polysilanes in the presence of N-ethoxy-2 methyl pyridinium bexafluorophosphate (EMP+PF6) and diphenyliodontum hexaffurophosphate (Ph2l+ PF6) was studied In the presence of the cationic salts the rate of photopolymerization was significantly increased The effect was attributed to the oxidation of silyl radicals formed from the photoscission of polysilane by pyndimum or diphenliodomum salts. The resulting radicals species are more capable of initiating the radical polymehzation.",

author = "Nergis Arsu and Gurkan Hizal and Yusuf Yagci",

year = "1995",

doi = "10.1080/10601329508020347",

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T1 - The effect of cationic salt on photoinitiated free radical polymerization using polysilanes

AU - Arsu, Nergis

AU - Hizal, Gurkan

AU - Yagci, Yusuf

PY - 1995

Y1 - 1995

N2 - Photoinitiated free radical polymerization of methylmethacrylate (MMA), (N-isopropyfcarbamate) ethylpropenoate (CL-960) and tripropyleneglycol diacrylate (TPGDA) by using polysilanes in the presence of N-ethoxy-2 methyl pyridinium bexafluorophosphate (EMP+PF6) and diphenyliodontum hexaffurophosphate (Ph2l+ PF6) was studied In the presence of the cationic salts the rate of photopolymerization was significantly increased The effect was attributed to the oxidation of silyl radicals formed from the photoscission of polysilane by pyndimum or diphenliodomum salts. The resulting radicals species are more capable of initiating the radical polymehzation.

AB - Photoinitiated free radical polymerization of methylmethacrylate (MMA), (N-isopropyfcarbamate) ethylpropenoate (CL-960) and tripropyleneglycol diacrylate (TPGDA) by using polysilanes in the presence of N-ethoxy-2 methyl pyridinium bexafluorophosphate (EMP+PF6) and diphenyliodontum hexaffurophosphate (Ph2l+ PF6) was studied In the presence of the cationic salts the rate of photopolymerization was significantly increased The effect was attributed to the oxidation of silyl radicals formed from the photoscission of polysilane by pyndimum or diphenliodomum salts. The resulting radicals species are more capable of initiating the radical polymehzation.

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DO - 10.1080/10601329508020347

M3 - Article

AN - SCOPUS:84949385711

SN - 1060-1325

VL - 32

SP - 1257

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JO - Journal of Macromolecular Science - Pure and Applied Chemistry

JF - Journal of Macromolecular Science - Pure and Applied Chemistry

IS - sup8

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The effect of cationic salt on photoinitiated free radical polymerization using polysilanes

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