Ternary SLE Measurements for the Systems H2O+ZnCl2+Zn(H2PO2)2 at T= (298, 313 and 333) K

Sevilay Demirci, Vedat Adigüzel*, Ömer Sahin, Hasan Erge

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Özet

The solid-liquid equilibrium (SLE) of H2O+ZnCl2+Zn(H2PO2)2 ternary system at 298, 313 and 333 K have been studied with the use of isothermal method. Solid phase compositions have been determined with Schreinemaker’s method. H2O+ZnCl2+Zn(H2PO2)2 ternary systems have simple eutectic type in 298, 333K. One invariant point, two invariant curves and two crystallization region have been observed in the phase diagrams at 298, 333K. Otherwise, One invariant point, three invariant curves and two crystallization region have been observed in the phase diagrams in 313K. In the crystallization regions; (i) Zn(H2PO2).H2 and ZnCl2, (ii) Zn(H2PO2)2, Zn(H2PO2).H2O and ZnCl2, (iii) Zn(H2PO2)2 and ZnCl2 salts have been observed at 298 K, 313K, and 333 K, respectively. In H2O+ZnCl2+Zn(H2PO2)2 ternary system, the increasing salting-out effect of Zn(H2PO2)2 on ZnCl2 with temperature.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)27-32
Sayfa sayısı6
DergiJournal of the Chemical Society of Pakistan
Hacim44
Basın numarası1
DOI'lar
Yayın durumuYayınlandı - Şub 2022
Harici olarak yayınlandıEvet

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Publisher Copyright:
© 2022 Chemical Society of Pakistan. All rights reserved.

Finansman

This work was supported by The Scientific and Technological Research Council of Turkey (TUBITAK) with project no:114Z651.

FinansörlerFinansör numarası
TUBITAK:114Z651
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

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