TY - JOUR
T1 - Synthetic routes to block copolymerization by changing mechanism from cationic polymerization to free radical polymerisation
AU - Yagoi, Yusuf
AU - Hizal, Gürkan
AU - Önen, Ayşen
AU - Serhatli, İErsin
PY - 1994/7
Y1 - 1994/7
N2 - Polymers containing thermolabile groups were synthesized by various cationic polymerization initiation mechanisms, namely; oxo–carbenium, promoted cationic and activated monomer polymerization. These polymers used in a subsequent blocking step in which azo groups were decomposed and converted into initiating centres from which blocks were grown by means of free radical polymerization. This procedure was applied to specific systems in which cationic polymerizable monomers are tetrahydrofuran (THF), cyclohexene oxide (CHO) and epichlorohydrin (ECH), respectively, and the free radical polymerizable monomer is styrene (St).
AB - Polymers containing thermolabile groups were synthesized by various cationic polymerization initiation mechanisms, namely; oxo–carbenium, promoted cationic and activated monomer polymerization. These polymers used in a subsequent blocking step in which azo groups were decomposed and converted into initiating centres from which blocks were grown by means of free radical polymerization. This procedure was applied to specific systems in which cationic polymerizable monomers are tetrahydrofuran (THF), cyclohexene oxide (CHO) and epichlorohydrin (ECH), respectively, and the free radical polymerizable monomer is styrene (St).
UR - http://www.scopus.com/inward/record.url?scp=84985379555&partnerID=8YFLogxK
U2 - 10.1002/masy.19940840116
DO - 10.1002/masy.19940840116
M3 - Article
AN - SCOPUS:84985379555
SN - 1022-1360
VL - 84
SP - 127
EP - 136
JO - Macromolecular Symposia
JF - Macromolecular Symposia
IS - 1
ER -