Synthesis, spectroscopic and electrochemical studies of bis(N-aryl-3,5-di-t-butyl-salicylaldiminato)cobalt(II) complexes

Veli T. Kasumov; Mustafa Özdemir; Esref Tas; Ömer Sahin

doi:10.1007/s11243-004-3333-3

Synthesis, spectroscopic and electrochemical studies of bis(N-aryl-3,5-di-t-butyl-salicylaldiminato)cobalt(II) complexes

Veli T. Kasumov^*
, Mustafa Özdemir
, Esref Tas
, Ömer Sahin

^*Bu çalışma için yazışmadan sorumlu yazar

Harran University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

5 Atıf (Scopus)

Özet

The synthesis and characterization (elemental analysis i.r. u.v. magnetic measurements and cyclic voltammetry) of some new Co^II complexes with bidentate bulky salicylaldimines derived from 35-di-t-butylsalicylaldehyde and o- or p-substituted (X = Cl Me OMe Bu ^t ) aniline derivatives are reported in this paper. The presented ligands show very low complexation ability in respect of Ni^II VO^II Mn^II Zn^II and Cd^II metal ions. Electrochemical studies on the complexes though revealing a dependence of the metal centered redox potentials on electronic and steric effects of the aniline substituents X the potentials of the ligand-centered oxidation do not correlate with the electronic effects of X.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	191-195
Sayfa sayısı	5
Dergi	Transition Metal Chemistry
Hacim	30
Basın numarası	2
DOI'lar	https://doi.org/10.1007/s11243-004-3333-3
Yayın durumu	Yayınlandı - Mar 2005
Harici olarak yayınlandı	Evet

Finansman

We thank the Research Fund of Harran University (Grant HUBAK-233) for research support.

Finansörler	Finansör numarası
Research Fund of Harran University	HUBAK-233

Belgeye Erişim

10.1007/s11243-004-3333-3

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis, spectroscopic and electrochemical studies of bis(N-aryl-3,5-di-t-butyl-salicylaldiminato)cobalt(II) complexes",

abstract = "The synthesis and characterization (elemental analysis i.r. u.v. magnetic measurements and cyclic voltammetry) of some new CoII complexes with bidentate bulky salicylaldimines derived from 35-di-t-butylsalicylaldehyde and o- or p-substituted (X = Cl Me OMe Bu t ) aniline derivatives are reported in this paper. The presented ligands show very low complexation ability in respect of NiII VOII MnII ZnII and CdII metal ions. Electrochemical studies on the complexes though revealing a dependence of the metal centered redox potentials on electronic and steric effects of the aniline substituents X the potentials of the ligand-centered oxidation do not correlate with the electronic effects of X.",

author = "Kasumov, \{Veli T.\} and Mustafa {\"O}zdemir and Esref Tas and {\"O}mer Sahin",

year = "2005",

month = mar,

doi = "10.1007/s11243-004-3333-3",

language = "English",

volume = "30",

pages = "191--195",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "2",

}

TY - JOUR

T1 - Synthesis, spectroscopic and electrochemical studies of bis(N-aryl-3,5-di-t-butyl-salicylaldiminato)cobalt(II) complexes

AU - Kasumov, Veli T.

AU - Özdemir, Mustafa

AU - Tas, Esref

AU - Sahin, Ömer

PY - 2005/3

Y1 - 2005/3

N2 - The synthesis and characterization (elemental analysis i.r. u.v. magnetic measurements and cyclic voltammetry) of some new CoII complexes with bidentate bulky salicylaldimines derived from 35-di-t-butylsalicylaldehyde and o- or p-substituted (X = Cl Me OMe Bu t ) aniline derivatives are reported in this paper. The presented ligands show very low complexation ability in respect of NiII VOII MnII ZnII and CdII metal ions. Electrochemical studies on the complexes though revealing a dependence of the metal centered redox potentials on electronic and steric effects of the aniline substituents X the potentials of the ligand-centered oxidation do not correlate with the electronic effects of X.

AB - The synthesis and characterization (elemental analysis i.r. u.v. magnetic measurements and cyclic voltammetry) of some new CoII complexes with bidentate bulky salicylaldimines derived from 35-di-t-butylsalicylaldehyde and o- or p-substituted (X = Cl Me OMe Bu t ) aniline derivatives are reported in this paper. The presented ligands show very low complexation ability in respect of NiII VOII MnII ZnII and CdII metal ions. Electrochemical studies on the complexes though revealing a dependence of the metal centered redox potentials on electronic and steric effects of the aniline substituents X the potentials of the ligand-centered oxidation do not correlate with the electronic effects of X.

UR - https://www.scopus.com/pages/publications/17544377554

U2 - 10.1007/s11243-004-3333-3

DO - 10.1007/s11243-004-3333-3

M3 - Article

AN - SCOPUS:17544377554

SN - 0340-4285

VL - 30

SP - 191

EP - 195

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 2

ER -

Synthesis, spectroscopic and electrochemical studies of bis(N-aryl-3,5-di-t-butyl-salicylaldiminato)cobalt(II) complexes

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

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