Synthesis of triglyceride-based urethane macromers and their use in copolymerization

Alev Koprululu; Aysen Onen; I. Ersin Serhatli; F. Seniha Guner

doi:10.1016/j.porgcoat.2008.06.006

Synthesis of triglyceride-based urethane macromers and their use in copolymerization

Alev Koprululu, Aysen Onen, I. Ersin Serhatli, F. Seniha Guner^*

^*Bu çalışma için yazışmadan sorumlu yazar

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

19 Atıf (Scopus)

Özet

Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and ¹H nuclear magnetic resonance (¹H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	365-371
Sayfa sayısı	7
Dergi	Progress in Organic Coatings
Hacim	63
Basın numarası	4
DOI'lar	https://doi.org/10.1016/j.porgcoat.2008.06.006
Yayın durumu	Yayınlandı - Kas 2008

Finansman

The financial support of ITU Research Fund is gratefully acknowledged.

Finansörler	Finansör numarası
ITU Research Fund

Belgeye Erişim

10.1016/j.porgcoat.2008.06.006

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis of triglyceride-based urethane macromers and their use in copolymerization",

abstract = "Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and 1H nuclear magnetic resonance (1H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.",

keywords = "Macromer, Triglyceride oil, Urethane",

author = "Alev Koprululu and Aysen Onen and Serhatli, {I. Ersin} and Guner, {F. Seniha}",

year = "2008",

month = nov,

doi = "10.1016/j.porgcoat.2008.06.006",

language = "English",

volume = "63",

pages = "365--371",

journal = "Progress in Organic Coatings",

issn = "0300-9440",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - Synthesis of triglyceride-based urethane macromers and their use in copolymerization

AU - Koprululu, Alev

AU - Onen, Aysen

AU - Serhatli, I. Ersin

AU - Guner, F. Seniha

PY - 2008/11

Y1 - 2008/11

N2 - Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and 1H nuclear magnetic resonance (1H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.

AB - Triglyceride oil-based urethane macromer (TGU) containing vinyl double bond was synthesized by the reaction of partial glyceride mixture (PGM) and methyl vinyl isocyanate (MVI). Free radical polymerization and copolymerization of TGU was studied. The structure of the TGU and polymers were elucidated by gel permeation chromatography (GPC) analysis, Fourier transform infrared spectroscopy (FT-IR) and 1H nuclear magnetic resonance (1H NMR) spectral measurements. The film properties of polymers were investigated by water resistance, alkali and acid resistance and contact angle measurements.

KW - Macromer

KW - Triglyceride oil

KW - Urethane

UR - http://www.scopus.com/inward/record.url?scp=55049092981&partnerID=8YFLogxK

U2 - 10.1016/j.porgcoat.2008.06.006

DO - 10.1016/j.porgcoat.2008.06.006

M3 - Article

AN - SCOPUS:55049092981

SN - 0300-9440

VL - 63

SP - 365

EP - 371

JO - Progress in Organic Coatings

JF - Progress in Organic Coatings

IS - 4

ER -

Synthesis of triglyceride-based urethane macromers and their use in copolymerization

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap