Synthesis of N,N′-diallylmalonamide and its copolymer gels with acrylic acid and acrylamide

Niyazi Biçak; Sevim Karaoǧlan; Bahire Filiz Senkal

doi:10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o

Synthesis of N,N′-diallylmalonamide and its copolymer gels with acrylic acid and acrylamide

Niyazi Biçak^*
, Sevim Karaoǧlan
, Bahire Filiz Senkal

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

1 Atıf (Scopus)

Özet

N,N′-diallylmalonamide (DAM) has been prepared via classical aminolysis of diethyl malonate with allylamine. Its structure was confirmed by elementary microanalysis as well as ¹H NMR and FT-IR spectroscopy. The new diallyl monomer is water-soluble and able to copolymerize radically with water-soluble monomers, such as acrylamide and acrylic acid, to give transparent hydrogels by using K₂S₂O₈ as initiator. Homopolymerization of DAM yields clear hydrogels with high swelling ability.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	13-16
Sayfa sayısı	4
Dergi	Angewandte Makromolekulare Chemie
Hacim	255
DOI'lar	https://doi.org/10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o
Yayın durumu	Yayınlandı - Mar 1998

Belgeye Erişim

10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis of N,N′-diallylmalonamide and its copolymer gels with acrylic acid and acrylamide",

abstract = "N,N′-diallylmalonamide (DAM) has been prepared via classical aminolysis of diethyl malonate with allylamine. Its structure was confirmed by elementary microanalysis as well as 1H NMR and FT-IR spectroscopy. The new diallyl monomer is water-soluble and able to copolymerize radically with water-soluble monomers, such as acrylamide and acrylic acid, to give transparent hydrogels by using K2S2O8 as initiator. Homopolymerization of DAM yields clear hydrogels with high swelling ability.",

author = "Niyazi Bi{\c c}ak and Sevim Karaoǧlan and Senkal, \{Bahire Filiz\}",

year = "1998",

month = mar,

doi = "10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o",

language = "English",

volume = "255",

pages = "13--16",

journal = "Angewandte Makromolekulare Chemie",

issn = "0003-3146",

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TY - JOUR

T1 - Synthesis of N,N′-diallylmalonamide and its copolymer gels with acrylic acid and acrylamide

AU - Biçak, Niyazi

AU - Karaoǧlan, Sevim

AU - Senkal, Bahire Filiz

PY - 1998/3

Y1 - 1998/3

N2 - N,N′-diallylmalonamide (DAM) has been prepared via classical aminolysis of diethyl malonate with allylamine. Its structure was confirmed by elementary microanalysis as well as 1H NMR and FT-IR spectroscopy. The new diallyl monomer is water-soluble and able to copolymerize radically with water-soluble monomers, such as acrylamide and acrylic acid, to give transparent hydrogels by using K2S2O8 as initiator. Homopolymerization of DAM yields clear hydrogels with high swelling ability.

AB - N,N′-diallylmalonamide (DAM) has been prepared via classical aminolysis of diethyl malonate with allylamine. Its structure was confirmed by elementary microanalysis as well as 1H NMR and FT-IR spectroscopy. The new diallyl monomer is water-soluble and able to copolymerize radically with water-soluble monomers, such as acrylamide and acrylic acid, to give transparent hydrogels by using K2S2O8 as initiator. Homopolymerization of DAM yields clear hydrogels with high swelling ability.

UR - https://www.scopus.com/pages/publications/0006967573

U2 - 10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o

DO - 10.1002/(sici)1522-9505(19980301)255:1<13::aid-apmc13>3.3.co;2-o

M3 - Article

AN - SCOPUS:0006967573

SN - 0003-3146

VL - 255

SP - 13

EP - 16

JO - Angewandte Makromolekulare Chemie

JF - Angewandte Makromolekulare Chemie

ER -

Synthesis of N,N′-diallylmalonamide and its copolymer gels with acrylic acid and acrylamide

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap