Synthesis of nickel nanoparticles by gamma irradiation and femtosecond laser ablation

Nickel nanoparticles were synthesized by (i) gamma irradiation of aqueous nickel chloride precursors and (ii) double scan femtosecond laser (FSL) ablation of a pure nickel foil in water. The nanoparticles produced by FSL ablation were further stabilized in acetone. Gamma radiolysis yielded nickel nanoparticles in the 2–22 nm range, with the average particle diameter governed by the total absorbed dose. Nickel nanoparticles produced by double scan FSL ablation were in the 2–17 nm range but less monodispersed than the nanoparticles produced via gamma radiolysis. FSL ablation proved to be superior in terms of yielding a higher number of smaller nanoparticles (< 10 nm).