Synthesis of hybrid liquid crystalline block copolymers by combination of cationic or promoted cationic and free-radical polymerizations

I. E. Serhatli*, G. Galli, Y. Yagci, E. Chiellini

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26 Atıf (Scopus)

Özet

The synthesis of two new classes of liquid crystalline block copolymers (1-5) by a two-step combination of cationic and free-radical polymerizations is described. An azomacroinitiator was prepared first by cationic polymerization of tetrahydrofuran or promoted cationic polymerization of cyclohexene oxide, which was then used to initiate the free-radical polymerization of an acrylate monomer containing a variously substituted biphenyl mesogenic group. The semicrystalline and liquid crystalline blocks were essentially microphase-separated and gave rise to different thermotropic mesophases.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)539-546
Sayfa sayısı8
DergiPolymer Bulletin
Hacim34
Basın numarası5-6
DOI'lar
Yayın durumuYayınlandı - Eyl 1995

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