Synthesis of highly functionalized γ-lactones via 1,5-electrocyclic ring closure

Olcay Anaç; F. Şeyma Güngör; Gökçe Merey

doi:10.1002/hlca.200690120

Synthesis of highly functionalized γ-lactones via 1,5-electrocyclic ring closure

Olcay Anaç^*
, F. Şeyma Güngör
, Gökçe Merey

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

14 Atıf (Scopus)

Özet

We have investigated 1,5-electrocyclic ring-closure reactions of conjugated esters with dimethyl diazomalonate in the presence of [Cu(acac)₂] as catalyst. Our new protocol offers an easy entry to various polyfunctionalized γ-lactones in high yields. Their subsequent derivatives may be used as valuable intermediates, especially in the synthesis of natural products and their analogues.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1231-1240
Sayfa sayısı	10
Dergi	Helvetica Chimica Acta
Hacim	89
Basın numarası	6
DOI'lar	https://doi.org/10.1002/hlca.200690120
Yayın durumu	Yayınlandı - 2006

Belgeye Erişim

10.1002/hlca.200690120

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis of highly functionalized γ-lactones via 1,5-electrocyclic ring closure",

abstract = "We have investigated 1,5-electrocyclic ring-closure reactions of conjugated esters with dimethyl diazomalonate in the presence of [Cu(acac)2] as catalyst. Our new protocol offers an easy entry to various polyfunctionalized γ-lactones in high yields. Their subsequent derivatives may be used as valuable intermediates, especially in the synthesis of natural products and their analogues.",

author = "Olcay Ana{\c c} and G{\"u}ng{\"o}r, \{F. {\c S}eyma\} and G{\"o}k{\c c}e Merey",

year = "2006",

doi = "10.1002/hlca.200690120",

language = "English",

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pages = "1231--1240",

journal = "Helvetica Chimica Acta",

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T1 - Synthesis of highly functionalized γ-lactones via 1,5-electrocyclic ring closure

AU - Anaç, Olcay

AU - Güngör, F. Şeyma

AU - Merey, Gökçe

PY - 2006

Y1 - 2006

N2 - We have investigated 1,5-electrocyclic ring-closure reactions of conjugated esters with dimethyl diazomalonate in the presence of [Cu(acac)2] as catalyst. Our new protocol offers an easy entry to various polyfunctionalized γ-lactones in high yields. Their subsequent derivatives may be used as valuable intermediates, especially in the synthesis of natural products and their analogues.

AB - We have investigated 1,5-electrocyclic ring-closure reactions of conjugated esters with dimethyl diazomalonate in the presence of [Cu(acac)2] as catalyst. Our new protocol offers an easy entry to various polyfunctionalized γ-lactones in high yields. Their subsequent derivatives may be used as valuable intermediates, especially in the synthesis of natural products and their analogues.

UR - https://www.scopus.com/pages/publications/33745784168

U2 - 10.1002/hlca.200690120

DO - 10.1002/hlca.200690120

M3 - Article

AN - SCOPUS:33745784168

SN - 0018-019X

VL - 89

SP - 1231

EP - 1240

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 6

ER -

Synthesis of highly functionalized γ-lactones via 1,5-electrocyclic ring closure

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap