Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

Metin H. Acar; Niyazi Bicak

doi:10.1002/pola.10716

Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

Metin H. Acar^*
, Niyazi Bicak

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Massachusetts Institute of Technology
Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

38 Atıf (Scopus)

Özet

The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr₂ was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1677-1680
Sayfa sayısı	4
Dergi	Journal of Polymer Science, Part A: Polymer Chemistry
Hacim	41
Basın numarası	11
DOI'lar	https://doi.org/10.1002/pola.10716
Yayın durumu	Yayınlandı - 1 Haz 2003

Belgeye Erişim

10.1002/pola.10716

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Link to publication in Scopus

Alıntı Yap

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title = "Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization",

abstract = "The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.",

keywords = "Atom transfer radical polymerization (ATRP), Homogeneous polymerization, Ligand, Living radical polymerization, Metal-organic catalysts / organometallic catalysts",

author = "Acar, \{Metin H.\} and Niyazi Bicak",

year = "2003",

month = jun,

day = "1",

doi = "10.1002/pola.10716",

language = "English",

volume = "41",

pages = "1677--1680",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

number = "11",

}

TY - JOUR

T1 - Synthesis of hexylated triethylenetetramine

T2 - New ligand for homogeneous atom transfer radical polymerization

AU - Acar, Metin H.

AU - Bicak, Niyazi

PY - 2003/6/1

Y1 - 2003/6/1

N2 - The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

AB - The synthesis of hexylated triethylenetetramine (HHTETA), a ligand for homogenous atom transfer radical polymerization (ATRP), was discussed. It was found that when HHTETA was dissolved in S, CuBr and CuBr2 was extracted from aqueous solutions almost quantitatively. The use of HHTETA as a ligand for copper-mediated ATRP in suspension or emulsion polymerization processes was also elaborated.

KW - Atom transfer radical polymerization (ATRP)

KW - Homogeneous polymerization

KW - Ligand

KW - Living radical polymerization

KW - Metal-organic catalysts / organometallic catalysts

UR - https://www.scopus.com/pages/publications/0037809270

U2 - 10.1002/pola.10716

DO - 10.1002/pola.10716

M3 - Article

AN - SCOPUS:0037809270

SN - 0887-624X

VL - 41

SP - 1677

EP - 1680

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 11

ER -

Synthesis of hexylated triethylenetetramine: New ligand for homogeneous atom transfer radical polymerization

Özet

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Diğer Dosyalar ve Linkler

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