Synthesis of ferrocenyl quinones

Metin Zora; Baris Yucel; Serdar Acikalin

doi:10.1016/S0040-4039(03)00099-6

Synthesis of ferrocenyl quinones

Metin Zora, Baris Yucel, Serdar Acikalin

Middle East Technical University

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

37 Atıf (Scopus)

Özet

A squarate-based synthesis of ferrocenyl quinones is described. Thermolysis of ferrocenyl-substituted cyclobutenones, prepared from ferrocenyl cyclobutenediones and alkenyllithiums, affords hydroquinones, which furnish, upon oxidation, ferrocenyl quinones. Ferrocenyl cyclobutenediones have been prepared from known cyclobutenediones by nucleophilic addition of ferrocenyllithium followed by hydrolysis, Pd/Cu-cocatalyzed cross-coupling with (tri-n-butylstannyl)ferrocene or Friedel-Crafts alkylation with ferrocene.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	2237-2241
Sayfa sayısı	5
Dergi	Tetrahedron Letters
Hacim	44
Basın numarası	10
DOI'lar	https://doi.org/10.1016/S0040-4039(03)00099-6
Yayın durumu	Yayınlandı - 3 Mar 2003
Harici olarak yayınlandı	Evet

Belgeye Erişim

10.1016/S0040-4039(03)00099-6

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@article{d6779cf591dc483796d0e3e3bbb0cdda,

title = "Synthesis of ferrocenyl quinones",

abstract = "A squarate-based synthesis of ferrocenyl quinones is described. Thermolysis of ferrocenyl-substituted cyclobutenones, prepared from ferrocenyl cyclobutenediones and alkenyllithiums, affords hydroquinones, which furnish, upon oxidation, ferrocenyl quinones. Ferrocenyl cyclobutenediones have been prepared from known cyclobutenediones by nucleophilic addition of ferrocenyllithium followed by hydrolysis, Pd/Cu-cocatalyzed cross-coupling with (tri-n-butylstannyl)ferrocene or Friedel-Crafts alkylation with ferrocene.",

keywords = "Cyclobutenediones, Cyclobutenols, Cyclobutenones, Electrocyclization, Ferrocenes, Ferrocenyl quinones, Hydroquinones, Oxidation",

author = "Metin Zora and Baris Yucel and Serdar Acikalin",

year = "2003",

month = mar,

day = "3",

doi = "10.1016/S0040-4039(03)00099-6",

language = "English",

volume = "44",

pages = "2237--2241",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "10",

}

TY - JOUR

T1 - Synthesis of ferrocenyl quinones

AU - Zora, Metin

AU - Yucel, Baris

AU - Acikalin, Serdar

PY - 2003/3/3

Y1 - 2003/3/3

N2 - A squarate-based synthesis of ferrocenyl quinones is described. Thermolysis of ferrocenyl-substituted cyclobutenones, prepared from ferrocenyl cyclobutenediones and alkenyllithiums, affords hydroquinones, which furnish, upon oxidation, ferrocenyl quinones. Ferrocenyl cyclobutenediones have been prepared from known cyclobutenediones by nucleophilic addition of ferrocenyllithium followed by hydrolysis, Pd/Cu-cocatalyzed cross-coupling with (tri-n-butylstannyl)ferrocene or Friedel-Crafts alkylation with ferrocene.

AB - A squarate-based synthesis of ferrocenyl quinones is described. Thermolysis of ferrocenyl-substituted cyclobutenones, prepared from ferrocenyl cyclobutenediones and alkenyllithiums, affords hydroquinones, which furnish, upon oxidation, ferrocenyl quinones. Ferrocenyl cyclobutenediones have been prepared from known cyclobutenediones by nucleophilic addition of ferrocenyllithium followed by hydrolysis, Pd/Cu-cocatalyzed cross-coupling with (tri-n-butylstannyl)ferrocene or Friedel-Crafts alkylation with ferrocene.

KW - Cyclobutenediones

KW - Cyclobutenols

KW - Cyclobutenones

KW - Electrocyclization

KW - Ferrocenes

KW - Ferrocenyl quinones

KW - Hydroquinones

KW - Oxidation

UR - http://www.scopus.com/inward/record.url?scp=0037416899&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(03)00099-6

DO - 10.1016/S0040-4039(03)00099-6

M3 - Article

AN - SCOPUS:0037416899

SN - 0040-4039

VL - 44

SP - 2237

EP - 2241

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 10

ER -

Synthesis of ferrocenyl quinones

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