Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

Cansu Aydogan; F. Simal Aykac; Gorkem Yilmaz; Ye Qiu Chew; Atsushi Goto; Yusuf Yagci

doi:10.1021/acsmacrolett.2c00004

Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

Cansu Aydogan
, F. Simal Aykac
, Gorkem Yilmaz
, Ye Qiu Chew
, Atsushi Goto^*
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Nanyang Technological University
Faculty of Sciences, King Abdulaziz University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

8 Atıf (Scopus)

Özet

A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by ¹H NMR, FT-IR, GPC, and DSC investigations.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	342-346
Sayfa sayısı	5
Dergi	ACS Macro Letters
Hacim	11
Basın numarası	3
DOI'lar	https://doi.org/10.1021/acsmacrolett.2c00004
Yayın durumu	Yayınlandı - 15 Mar 2022

Bibliyografik not

Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.

Finansman

The authors acknowledge the financial support from The Scientific and Technological Research Council of Turkey (Project 120C121) and the Istanbul Technical University Research Fund and National Research Foundation (NRF) Investigatorship in Singapore (NRF-NRFI05-2019-0001).

Finansörler	Finansör numarası
Istanbul Technical University Research Fund
National Research Foundation Singapore	NRF-NRFI05-2019-0001
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	120C121

Belgeye Erişim

10.1021/acsmacrolett.2c00004

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{c492f596e1b94628824ac68f8b53eafe,

title = "Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process",

abstract = "A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.",

author = "Cansu Aydogan and Aykac, \{F. Simal\} and Gorkem Yilmaz and Chew, \{Ye Qiu\} and Atsushi Goto and Yusuf Yagci",

year = "2022",

month = mar,

day = "15",

doi = "10.1021/acsmacrolett.2c00004",

language = "English",

volume = "11",

pages = "342--346",

journal = "ACS Macro Letters",

issn = "2161-1653",

publisher = "American Chemical Society",

number = "3",

}

Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process. / Aydogan, Cansu; Aykac, F. Simal; Yilmaz, Gorkem et al.
In: ACS Macro Letters, Hac. 11, No. 3, 15.03.2022, p. 342-346.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

AU - Aydogan, Cansu

AU - Aykac, F. Simal

AU - Yilmaz, Gorkem

AU - Chew, Ye Qiu

AU - Goto, Atsushi

AU - Yagci, Yusuf

PY - 2022/3/15

Y1 - 2022/3/15

N2 - A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.

AB - A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques-reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes-is reported. First, RCMP is conducted to yield poly(methyl methacrylate) with iodide end groups (PMMA-I). In the following step, PMMA-I is used as macroinitiator for living PROAD cationic polymerization of isobutyl vinyl ether. Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.

UR - https://www.scopus.com/pages/publications/85125922391

U2 - 10.1021/acsmacrolett.2c00004

DO - 10.1021/acsmacrolett.2c00004

M3 - Article

C2 - 35575368

AN - SCOPUS:85125922391

SN - 2161-1653

VL - 11

SP - 342

EP - 346

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 3

ER -

Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap