Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

Ayfer Yildirim; Baris Kiskan; A. Levent Demirel; Yusuf Yagci

doi:10.1016/j.eurpolymj.2006.07.019

Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

Ayfer Yildirim
, Baris Kiskan
, A. Levent Demirel
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Koc University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

79 Atıf (Scopus)

Özet

Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and ¹H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	3006-3014
Sayfa sayısı	9
Dergi	European Polymer Journal
Hacim	42
Basın numarası	11
DOI'lar	https://doi.org/10.1016/j.eurpolymj.2006.07.019
Yayın durumu	Yayınlandı - Kas 2006

Finansman

The authors would like to thank DPT (Turkish State Planning Association), Project no: 90192, for the financial support.

Finansörler	Finansör numarası
Turkish State Planning Association	90192

Belgeye Erişim

10.1016/j.eurpolymj.2006.07.019

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{b34a261fd9d84ff78f3c73eb771c1c23,

title = "Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s",

abstract = "Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and 1H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).",

keywords = "Naphthoxazine, Poly(propyleneoxide) amine, Polybenzoxazine, Thermoset",

author = "Ayfer Yildirim and Baris Kiskan and Demirel, \{A. Levent\} and Yusuf Yagci",

year = "2006",

month = nov,

doi = "10.1016/j.eurpolymj.2006.07.019",

language = "English",

volume = "42",

pages = "3006--3014",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd",

number = "11",

}

TY - JOUR

T1 - Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

AU - Yildirim, Ayfer

AU - Kiskan, Baris

AU - Demirel, A. Levent

AU - Yagci, Yusuf

PY - 2006/11

Y1 - 2006/11

N2 - Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and 1H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).

AB - Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and 1H-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM).

KW - Naphthoxazine

KW - Poly(propyleneoxide) amine

KW - Polybenzoxazine

KW - Thermoset

UR - https://www.scopus.com/pages/publications/33750031039

U2 - 10.1016/j.eurpolymj.2006.07.019

DO - 10.1016/j.eurpolymj.2006.07.019

M3 - Article

AN - SCOPUS:33750031039

SN - 0014-3057

VL - 42

SP - 3006

EP - 3014

JO - European Polymer Journal

JF - European Polymer Journal

IS - 11

ER -

Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap