Synthesis, characterization and OFET property of four diaminouracil bridged novel ball-type phthalocyanines

Ayşegül Yazlcl; Ayşe Avcl; Ahmet Altlndal; Bekir Salih; Özer Bekaroǧlu

doi:10.1142/S1088424618500049

Synthesis, characterization and OFET property of four diaminouracil bridged novel ball-type phthalocyanines

Ayşegül Yazlcl
, Ayşe Avcl
, Ahmet Altlndal^*
, Bekir Salih
, Özer Bekaroǧlu

^*Bu çalışma için yazışmadan sorumlu yazar

Firat University
Yildiz Technical University
Hacettepe University
Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

9 Atıf (Scopus)

Özet

New ball-type metallobisphthalocyanines 2 (Co2Pc2) and 3(Zn2Pc2) were synthesized from the corresponding 4,4′-[(5,6-diaminopyrimidine-2,4-diyl)bis(oxy)] diphytalonitril 1, which can be obtained by a nucleophilic displacement reaction of 4-nitrophthalonitrile with 5,6-diaminouracil sulfate. Characterization of novel compounds was performed by UV-vis, FT-IR, 1H-NMR, MALDI-TOF mass spectroscopy and elemental analysis. Organic field effect transistor devices (OFETs) with top gate structure were fabricated using these novel compounds as the active material. The devices were characterized by means of their output and transfer characteristics, and it was found that these OFET devices exhibit p-type behavior. When compared with the 2-based device, the OFET with 3 showed higher field effect mobility and larger on/of current ratio.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	149-156
Sayfa sayısı	8
Dergi	Journal of Porphyrins and Phthalocyanines
Hacim	22
Basın numarası	1-3
DOI'lar	https://doi.org/10.1142/S1088424618500049
Yayın durumu	Yayınlandı - 2018
Harici olarak yayınlandı	Evet

Bibliyografik not

Publisher Copyright:
© 2018 World Scientific Publishing Company.

Finansman

We are grateful to Fırat University Scientific Research Project Coordination Unit, FÜBAP, for their financial support (Project No: FF.13.31), Yıldız Technical University Commission of Scientific Research Projects (2016-0101KAP04) and Turkish Academy of Sciences, TUBA, for the partial financial support.

Finansörler	Finansör numarası
Fırat University
TUBA
Yıldız Technical University	2016-0101KAP04
Türkiye Bilimler Akademisi
Firat University Scientific Research Projects Management Unit	FF.13.31

Belgeye Erişim

10.1142/S1088424618500049

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis, characterization and OFET property of four diaminouracil bridged novel ball-type phthalocyanines",

abstract = "New ball-type metallobisphthalocyanines 2 (Co2Pc2) and 3(Zn2Pc2) were synthesized from the corresponding 4,4′-[(5,6-diaminopyrimidine-2,4-diyl)bis(oxy)] diphytalonitril 1, which can be obtained by a nucleophilic displacement reaction of 4-nitrophthalonitrile with 5,6-diaminouracil sulfate. Characterization of novel compounds was performed by UV-vis, FT-IR, 1H-NMR, MALDI-TOF mass spectroscopy and elemental analysis. Organic field effect transistor devices (OFETs) with top gate structure were fabricated using these novel compounds as the active material. The devices were characterized by means of their output and transfer characteristics, and it was found that these OFET devices exhibit p-type behavior. When compared with the 2-based device, the OFET with 3 showed higher field effect mobility and larger on/of current ratio.",

keywords = "OFET, ball-type phthalocyanines, field effect, homodinuclear, threshold voltage",

author = "Ay{\c s}eg{\"u}l Yazlcl and Ay{\c s}e Avcl and Ahmet Altlndal and Bekir Salih and {\"O}zer Bekaroǧlu",

note = "Publisher Copyright: {\textcopyright} 2018 World Scientific Publishing Company.",

year = "2018",

doi = "10.1142/S1088424618500049",

language = "English",

volume = "22",

pages = "149--156",

journal = "Journal of Porphyrins and Phthalocyanines",

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publisher = "World Scientific",

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TY - JOUR

T1 - Synthesis, characterization and OFET property of four diaminouracil bridged novel ball-type phthalocyanines

AU - Yazlcl, Ayşegül

AU - Avcl, Ayşe

AU - Altlndal, Ahmet

AU - Salih, Bekir

AU - Bekaroǧlu, Özer

PY - 2018

Y1 - 2018

N2 - New ball-type metallobisphthalocyanines 2 (Co2Pc2) and 3(Zn2Pc2) were synthesized from the corresponding 4,4′-[(5,6-diaminopyrimidine-2,4-diyl)bis(oxy)] diphytalonitril 1, which can be obtained by a nucleophilic displacement reaction of 4-nitrophthalonitrile with 5,6-diaminouracil sulfate. Characterization of novel compounds was performed by UV-vis, FT-IR, 1H-NMR, MALDI-TOF mass spectroscopy and elemental analysis. Organic field effect transistor devices (OFETs) with top gate structure were fabricated using these novel compounds as the active material. The devices were characterized by means of their output and transfer characteristics, and it was found that these OFET devices exhibit p-type behavior. When compared with the 2-based device, the OFET with 3 showed higher field effect mobility and larger on/of current ratio.

AB - New ball-type metallobisphthalocyanines 2 (Co2Pc2) and 3(Zn2Pc2) were synthesized from the corresponding 4,4′-[(5,6-diaminopyrimidine-2,4-diyl)bis(oxy)] diphytalonitril 1, which can be obtained by a nucleophilic displacement reaction of 4-nitrophthalonitrile with 5,6-diaminouracil sulfate. Characterization of novel compounds was performed by UV-vis, FT-IR, 1H-NMR, MALDI-TOF mass spectroscopy and elemental analysis. Organic field effect transistor devices (OFETs) with top gate structure were fabricated using these novel compounds as the active material. The devices were characterized by means of their output and transfer characteristics, and it was found that these OFET devices exhibit p-type behavior. When compared with the 2-based device, the OFET with 3 showed higher field effect mobility and larger on/of current ratio.

KW - OFET

KW - ball-type phthalocyanines

KW - field effect

KW - homodinuclear

KW - threshold voltage

UR - https://www.scopus.com/pages/publications/85040940792

U2 - 10.1142/S1088424618500049

DO - 10.1142/S1088424618500049

M3 - Article

AN - SCOPUS:85040940792

SN - 1088-4246

VL - 22

SP - 149

EP - 156

JO - Journal of Porphyrins and Phthalocyanines

JF - Journal of Porphyrins and Phthalocyanines

IS - 1-3

ER -

Synthesis, characterization and OFET property of four diaminouracil bridged novel ball-type phthalocyanines

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

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