Synthesis and some optical results of long chain substituted phthalocyanines

Ibrahim Özçeşmeci*, Idris Sorar

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Özet

Four metallo (zinc, copper, vanadyl, and indium) phthalocyanine derivatives bearing four aliphatic (hexylthio) groups were prepared from corresponding phthalonitrile compounds. The metallophthalocyanines were characterized with ultraviolet–visible spectroscopy (UV-Vis), proton nuclear magnetic resonance (1 H NMR), Fourier transform-infrared spectroscopy (FT- IR), and mass and elemental analyses techniques. Aggregation properties of metallophthalocyanines in solution were studied in varied concentration ranges. Thin films of metallophthalocyanines were obtained by spin coating technique. Optical measurements showed that transmittance values of metallophthalocyanine thin films obviously changed with respect to the metal ion in the phthalocyanines. Transmittance spectra of the phthalocyanines synthesized using different metal ions showed a variation of about 8% and 15% in transmittance spectra of the Q band region was obtained by mixing the two metal phthalocyanine (indium and zinc) solutions.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)21-28
Sayfa sayısı8
DergiTurkish Journal of Chemistry
Hacim42
Basın numarası1
DOI'lar
Yayın durumuYayınlandı - 2018

Bibliyografik not

Publisher Copyright:
© TÜBITAK.

Finansman

This work was supported by the Research Funds of İstanbul Technical University.

FinansörlerFinansör numarası
Istanbul Teknik Üniversitesi

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