Synthesis and mesophase properties of block and random co-polymers of electroactive and liquid crystalline monomers

Faruk Yilmaz, Fatmanur Kasapoglu, Yesim Hepuzer, Yusuf Yagci*, Levent Toppare, Elizabeth Grillo Fernandes, Giancarlo Galli

*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: Dergiye katkıMakalebilirkişi

14 Atıf (Scopus)

Özet

Homo-polymers and random co-polymers of electroactive and liquid crystalline monomers, namely 3-thienylmethyl methacrylate (MTM) and 6-(4-cyanobiphenyl-4′-oxy)hexyl acrylate (LC6), were prepared by conventional free radical polymerization. Block co-polymers of MTM and LC6 were also synthesized by using the 1,1-diphenylethene (DPE) method. The obtained random and block co-polymers exhibited liquid crystal behavior depending on the content of the LC6 units. It was found that microphase separation of the polymer blocks is an effective means to stabilize the mesophase in the block co-polymers relative to compositionally similar random co-polymers.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)223-236
Sayfa sayısı14
DergiDesigned Monomers and Polymers
Hacim8
Basın numarası3
DOI'lar
Yayın durumuYayınlandı - 2005

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