Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

S. Topal; R. Isci; E. Sezer; T. Ozturk; B. Ustamehmetoglu

doi:10.1016/j.electacta.2021.138688

Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

S. Topal, R. Isci, E. Sezer, T. Ozturk, B. Ustamehmetoglu^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

22 Atıf (Scopus)

Özet

Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH₃OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH₃OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH₃OPhTTTPA] and P[CNPhTTTPA] were obtained, respectively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong electron withdrawing -CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character.

Orijinal dil	İngilizce
Makale numarası	138688
Dergi	Electrochimica Acta
Hacim	389
DOI'lar	https://doi.org/10.1016/j.electacta.2021.138688
Yayın durumu	Yayınlandı - 1 Eyl 2021

Bibliyografik not

Publisher Copyright:
© 2021

Finansman

We thank Istanbul Technical University Research Fund (Project number 42325 ) for financial supports and Higher Education Council of Turkey (YOK) and TUBITAK for grants to Sebahat Topal and Recep Isci (Ph.D., 100/2000 YOK, and TUBİTAK BIDEB 2211A). We thank Istanbul Technical University Research Fund (Project number 42325) for financial supports and Higher Education Council of Turkey (YOK) and TUBITAK for grants to Sebahat Topal and Recep Isci (Ph.D. 100/2000 YOK, and TUB?TAK BIDEB 2211A).

Finansörler	Finansör numarası
Higher Education Council of Turkey
Istanbul Technical University Research Fund	42325
TUBITAK	100/2000 YOK
TUBİTAK	BIDEB 2211A
YOK

Belgeye Erişim

10.1016/j.electacta.2021.138688

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{9d717a5d49d242458e5a100a6f901a3f,

title = "Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers",

abstract = "Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH3OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH3OPhTTTPA] and P[CNPhTTTPA] were obtained, respectively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong electron withdrawing -CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character.",

keywords = "Cyanophenyl, Electrochemical polymerization, Methoxyphenyl, Phenyl, Thieno[3,2-b]thiophene, Triphenylamine",

author = "S. Topal and R. Isci and E. Sezer and T. Ozturk and B. Ustamehmetoglu",

note = "Publisher Copyright: {\textcopyright} 2021",

year = "2021",

month = sep,

day = "1",

doi = "10.1016/j.electacta.2021.138688",

language = "English",

volume = "389",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

AU - Topal, S.

AU - Isci, R.

AU - Sezer, E.

AU - Ozturk, T.

AU - Ustamehmetoglu, B.

PY - 2021/9/1

Y1 - 2021/9/1

N2 - Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH3OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH3OPhTTTPA] and P[CNPhTTTPA] were obtained, respectively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong electron withdrawing -CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character.

AB - Electrochemical polymerizations of thieno[3,2-b]thiophenes (TT), named PhTTTPA, CH3OPhTTTPA and CNPhTTTPA, possessing pH, 4-CH3OPh, 4-CNPh and triphenylamine (TPA) units, were performed and their corresponding polymers P[PhTTTPA], P[CH3OPhTTTPA] and P[CNPhTTTPA] were obtained, respectively. The polymer films were characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and spectroelectrochemical measurements, which suggested that while the presence of strong electron donating TPA unit provided them with better electrochemical reversibility, strong electron withdrawing -CN group lowered the oxidation potential of P[CNPhTTTPA] along with enhancement of its charge storage character.

KW - Cyanophenyl

KW - Electrochemical polymerization

KW - Methoxyphenyl

KW - Phenyl

KW - Thieno[3,2-b]thiophene

KW - Triphenylamine

UR - http://www.scopus.com/inward/record.url?scp=85107797684&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2021.138688

DO - 10.1016/j.electacta.2021.138688

M3 - Article

AN - SCOPUS:85107797684

SN - 0013-4686

VL - 389

JO - Electrochimica Acta

JF - Electrochimica Acta

M1 - 138688

ER -

Synthesis and electropolymerization of 3-arylthieno[3,2-b]thiophenes and triphenylamine based comonomers

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap