Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, Mn(CO) 3Cp] with salicylaldehyde methanesulfonylhydrazone

S. Sert; O. S. Şentürk; Ü Özdemir; N. Karacan; F. Ugur

doi:10.1080/00958970410001666170

Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)₆ (M = Cr, Mo, W), Re(CO)₅Br, Mn(CO) ₃Cp] with salicylaldehyde methanesulfonylhydrazone

S. Sert
, O. S. Şentürk^*
, Ü Özdemir
, N. Karacan
, F. Ugur

^*Bu çalışma için yazışmadan sorumlu yazar

Ege University
National Research Council of Canada
Gazi University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

29 Atıf (Scopus)

Özet

Five new complexes, [M(CO)₅(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)₄Br(salmsh)], 4, and [Mn(CO)₃ (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and ¹H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	183-188
Sayfa sayısı	6
Dergi	Journal of Coordination Chemistry
Hacim	57
Basın numarası	3
DOI'lar	https://doi.org/10.1080/00958970410001666170
Yayın durumu	Yayınlandı - 15 Şub 2004
Harici olarak yayınlandı	Evet

Finansman

We thank BP (Turkey) for the provision of photochemical apparatus and the Research Foundation of Ege and Gazi University for funds. We thank TUBITAK_ for allocation of time for NMR, mass spectra and elemental analyses.

Finansörler
Research Foundation of Ege and Gazi University
BP

Belgeye Erişim

10.1080/00958970410001666170

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, Mn(CO) 3Cp] with salicylaldehyde methanesulfonylhydrazone",

abstract = "Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.",

keywords = "Metal carbonyls, Methanesulfonylhydrazone, Salicylaldehyde, Sulfonylhydrazone",

author = "S. Sert and {\c S}ent{\"u}rk, \{O. S.\} and {\"U} {\"O}zdemir and N. Karacan and F. Ugur",

year = "2004",

month = feb,

day = "15",

doi = "10.1080/00958970410001666170",

language = "English",

volume = "57",

pages = "183--188",

journal = "Journal of Coordination Chemistry",

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TY - JOUR

T1 - Synthesis and characterization of the products from reaction of metal carbonyls [M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, Mn(CO) 3Cp] with salicylaldehyde methanesulfonylhydrazone

AU - Sert, S.

AU - Şentürk, O. S.

AU - Özdemir, Ü

AU - Karacan, N.

AU - Ugur, F.

PY - 2004/2/15

Y1 - 2004/2/15

N2 - Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

AB - Five new complexes, [M(CO)5(salmsh)] (M=Cr;1,Mo;2,W;3), [Re(CO)4Br(salmsh)], 4, and [Mn(CO)3 (salmsh)], 5, have been synthesized by the photochemical reaction of metal carbonyls with salicylaldehyde methanesulfonylhydrazone (salmsh). The complexes have been characterized by elemental analyses, E1 mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that salmsh behaves as a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

KW - Metal carbonyls

KW - Methanesulfonylhydrazone

KW - Salicylaldehyde

KW - Sulfonylhydrazone

UR - https://www.scopus.com/pages/publications/2442500652

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DO - 10.1080/00958970410001666170

M3 - Article

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SN - 0095-8972

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SP - 183

EP - 188

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

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