Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

Ozan Sanli Şentürk; Ümmühan Özdemir; Sema Sert; Nurcan Karacan; Fadime Uǧur

doi:10.1016/S1387-7003(03)00152-7

Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

Ozan Sanli Şentürk^*
, Ümmühan Özdemir
, Sema Sert
, Nurcan Karacan
, Fadime Uǧur

^*Bu çalışma için yazışmadan sorumlu yazar

Ege University
National Research Council of Canada
Gazi University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

16 Atıf (Scopus)

Özet

Five new complexes, [M(CO)₅(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)₄ Br(apesh)] (4) and [Mn(CO)₃(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)₆] (M = Cr, Mo, W), [Re(CO)₅ Br], and [Mn(CO)₃ Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, ¹H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	926-929
Sayfa sayısı	4
Dergi	Inorganic Chemistry Communications
Hacim	6
Basın numarası	7
DOI'lar	https://doi.org/10.1016/S1387-7003(03)00152-7
Yayın durumu	Yayınlandı - 1 Tem 2003
Harici olarak yayınlandı	Evet

Finansman

We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. This research was also supported by Gazi University Research Found under Project No 05-98/24. We thank TUBİTAK for allocation of time at the NMR, Mass Spectra and Elemental Analyses.

Finansörler	Finansör numarası
Gazi University Research Found	05-98/24

Belgeye Erişim

10.1016/S1387-7003(03)00152-7

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{8dea87d89c59454da5ed71b1ee903893,

title = "Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone",

abstract = "Five new complexes, [M(CO)5(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4 Br(apesh)] (4) and [Mn(CO)3(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5 Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).",

keywords = "2-Hydroxyacetophenone ethanesulfonylhydrazone, Metal carbonyls, Photosubstituton",

author = "{\c S}ent{\"u}rk, \{Ozan Sanli\} and {\"U}mm{\"u}han {\"O}zdemir and Sema Sert and Nurcan Karacan and Fadime Uǧur",

year = "2003",

month = jul,

day = "1",

doi = "10.1016/S1387-7003(03)00152-7",

language = "English",

volume = "6",

pages = "926--929",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

AU - Şentürk, Ozan Sanli

AU - Özdemir, Ümmühan

AU - Sert, Sema

AU - Karacan, Nurcan

AU - Uǧur, Fadime

PY - 2003/7/1

Y1 - 2003/7/1

N2 - Five new complexes, [M(CO)5(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4 Br(apesh)] (4) and [Mn(CO)3(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5 Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).

AB - Five new complexes, [M(CO)5(apesh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4 Br(apesh)] (4) and [Mn(CO)3(apesh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5 Br], and [Mn(CO)3 Cp] with 2-hydroxyacetophenone ethanesulfonylhydrazone (apesh). The complexes have been characterized by elemental analysis, mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that apesh behaves as a monodentate ligand coordinating via imine N donor atom in (1)-(4) and as tridentate ligand in (5).

KW - 2-Hydroxyacetophenone ethanesulfonylhydrazone

KW - Metal carbonyls

KW - Photosubstituton

UR - https://www.scopus.com/pages/publications/0038038004

U2 - 10.1016/S1387-7003(03)00152-7

DO - 10.1016/S1387-7003(03)00152-7

M3 - Article

AN - SCOPUS:0038038004

SN - 1387-7003

VL - 6

SP - 926

EP - 929

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Synthesis and characterization of some metal carbonyls with 2-hydroxyacetophenone ethanesulfonylhydrazone

Özet

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