Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

Z. Altuntaş Bayir; E. Hamuryudan; A. G. Gürek; O. Bekaroǧlu

doi:10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

Z. Altuntaş Bayir
, E. Hamuryudan
, A. G. Gürek
, O. Bekaroǧlu^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Scientific and Technological Research Council of Turkey
Istanbul Technical University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

58 Atıf (Scopus)

Özet

The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl₂, CoCl₂ or Zn(O₂CMe)₂] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	349-353
Sayfa sayısı	5
Dergi	Journal of Porphyrins and Phthalocyanines
Hacim	1
Basın numarası	4
DOI'lar	https://doi.org/10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0
Yayın durumu	Yayınlandı - Eki 1997

Belgeye Erişim

10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines",

abstract = "The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.",

keywords = "Electrical conductivity, Pentanuclear complex, Phthalocyanine, Thiaethers",

author = "\{Altunta{\c s} Bayir\}, Z. and E. Hamuryudan and G{\"u}rek, \{A. G.\} and O. Bekaroǧlu",

year = "1997",

month = oct,

doi = "10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0",

language = "English",

volume = "1",

pages = "349--353",

journal = "Journal of Porphyrins and Phthalocyanines",

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}

TY - JOUR

T1 - Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

AU - Altuntaş Bayir, Z.

AU - Hamuryudan, E.

AU - Gürek, A. G.

AU - Bekaroǧlu, O.

PY - 1997/10

Y1 - 1997/10

N2 - The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.

AB - The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl2, CoCl2 or Zn(O2CMe)2] or hydroquinone. Zinc (II) phthalocyaninate reacted with palladium(II) salt to form complexes with a phthalocyanine (metal ratio of 1:4). The electrical conductivity of the phthalocyanines 2, 3, 5, 5a are in the semiconductor range.

KW - Electrical conductivity

KW - Pentanuclear complex

KW - Phthalocyanine

KW - Thiaethers

UR - https://www.scopus.com/pages/publications/0003099559

U2 - 10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

DO - 10.1002/(SICI)1099-1409(199710)1:4<349::AID-JPP38>3.3.CO;2-0

M3 - Article

AN - SCOPUS:0003099559

SN - 1088-4246

VL - 1

SP - 349

EP - 353

JO - Journal of Porphyrins and Phthalocyanines

JF - Journal of Porphyrins and Phthalocyanines

IS - 4

ER -

Synthesis and characterization of octakis (hydroxyethylthio)-substituted phthalocyanines

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap