Synthesis and characterization of novel soluble octa-cationic phthalocyanines

Zehra Altuntaş Bayir

doi:10.1016/j.dyepig.2004.08.003

Synthesis and characterization of novel soluble octa-cationic phthalocyanines

Zehra Altuntaş Bayir^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

93 Atıf (Scopus)

Özet

Metal-free 3 and metallophthalocyanines 4, 5 (M = Zn, Co) having diethylaminoethylsulfanyl substituents on peripheral positions were prepared. Quaternization of 4, 5 produced cationic metallophthalocyanines soluble in water and slightly soluble in ethanol. Zinc(II) and Co(II) phthalocyanines reacted with palladium(II) salt to form complexes with a phthalocyanine/metal ratio of 1:4. The new compounds have been characterized by elemental analyses, IR, UV-Vis, mass, ¹H NMR and ¹³C NMR spectroscopies.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	235-242
Sayfa sayısı	8
Dergi	Dyes and Pigments
Hacim	65
Basın numarası	3
DOI'lar	https://doi.org/10.1016/j.dyepig.2004.08.003
Yayın durumu	Yayınlandı - Haz 2005

Finansman

This work was supported by the Research Fund of the Technical University of Istanbul. The author is grateful to Dr. Atıf Koca for cyclic voltammetry measurements.

Finansörler	Finansör numarası
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1016/j.dyepig.2004.08.003

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{0f129e652d9b4be5987009de2de71098,

title = "Synthesis and characterization of novel soluble octa-cationic phthalocyanines",

abstract = "Metal-free 3 and metallophthalocyanines 4, 5 (M = Zn, Co) having diethylaminoethylsulfanyl substituents on peripheral positions were prepared. Quaternization of 4, 5 produced cationic metallophthalocyanines soluble in water and slightly soluble in ethanol. Zinc(II) and Co(II) phthalocyanines reacted with palladium(II) salt to form complexes with a phthalocyanine/metal ratio of 1:4. The new compounds have been characterized by elemental analyses, IR, UV-Vis, mass, 1H NMR and 13C NMR spectroscopies.",

keywords = "Cationic photosensitizers, Pentanuclear complexes, Phthalocyanines, Water-soluble",

author = "Bayir, {Zehra Altunta{\c s}}",

year = "2005",

month = jun,

doi = "10.1016/j.dyepig.2004.08.003",

language = "English",

volume = "65",

pages = "235--242",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Synthesis and characterization of novel soluble octa-cationic phthalocyanines

AU - Bayir, Zehra Altuntaş

PY - 2005/6

Y1 - 2005/6

N2 - Metal-free 3 and metallophthalocyanines 4, 5 (M = Zn, Co) having diethylaminoethylsulfanyl substituents on peripheral positions were prepared. Quaternization of 4, 5 produced cationic metallophthalocyanines soluble in water and slightly soluble in ethanol. Zinc(II) and Co(II) phthalocyanines reacted with palladium(II) salt to form complexes with a phthalocyanine/metal ratio of 1:4. The new compounds have been characterized by elemental analyses, IR, UV-Vis, mass, 1H NMR and 13C NMR spectroscopies.

AB - Metal-free 3 and metallophthalocyanines 4, 5 (M = Zn, Co) having diethylaminoethylsulfanyl substituents on peripheral positions were prepared. Quaternization of 4, 5 produced cationic metallophthalocyanines soluble in water and slightly soluble in ethanol. Zinc(II) and Co(II) phthalocyanines reacted with palladium(II) salt to form complexes with a phthalocyanine/metal ratio of 1:4. The new compounds have been characterized by elemental analyses, IR, UV-Vis, mass, 1H NMR and 13C NMR spectroscopies.

KW - Cationic photosensitizers

KW - Pentanuclear complexes

KW - Phthalocyanines

KW - Water-soluble

UR - http://www.scopus.com/inward/record.url?scp=10844276286&partnerID=8YFLogxK

U2 - 10.1016/j.dyepig.2004.08.003

DO - 10.1016/j.dyepig.2004.08.003

M3 - Article

AN - SCOPUS:10844276286

SN - 0143-7208

VL - 65

SP - 235

EP - 242

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 3

ER -

Synthesis and characterization of novel soluble octa-cationic phthalocyanines

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap