Synthesis and characterization of new unsymmetrically substituted phthalocyanines

Süleyman Gürsoy; Zehra A. Bayir; Esin Hamuryudan; Özer Bekaroǧlu

doi:10.1007/s007060070104

Synthesis and characterization of new unsymmetrically substituted phthalocyanines

Süleyman Gürsoy
, Zehra A. Bayir
, Esin Hamuryudan
, Özer Bekaroǧlu^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

25 Atıf (Scopus)

Özet

Unsymmetric metallophthalocyanines (M = Zn, Co, Ni) carrying alkylthio and acetyl-oxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH₃COO)₂, NiCl₂, and CoCl₂. The extremely soluble compounds were characterized by their IR, ¹H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	287-292
Sayfa sayısı	6
Dergi	Monatshefte fur Chemie
Hacim	131
Basın numarası	3
DOI'lar	https://doi.org/10.1007/s007060070104
Yayın durumu	Yayınlandı - 2000

Belgeye Erişim

10.1007/s007060070104

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Link to publication in Scopus

Alıntı Yap

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title = "Synthesis and characterization of new unsymmetrically substituted phthalocyanines",

abstract = "Unsymmetric metallophthalocyanines (M = Zn, Co, Ni) carrying alkylthio and acetyl-oxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The extremely soluble compounds were characterized by their IR, 1H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.",

keywords = "Alkylthio derivatives, Phthalocyanines, Unsymmetrical substituents",

author = "S{\"u}leyman G{\"u}rsoy and Bayir, \{Zehra A.\} and Esin Hamuryudan and {\"O}zer Bekaroǧlu",

year = "2000",

doi = "10.1007/s007060070104",

language = "English",

volume = "131",

pages = "287--292",

journal = "Monatshefte fur Chemie",

issn = "0026-9247",

publisher = "Springer",

number = "3",

}

TY - JOUR

T1 - Synthesis and characterization of new unsymmetrically substituted phthalocyanines

AU - Gürsoy, Süleyman

AU - Bayir, Zehra A.

AU - Hamuryudan, Esin

AU - Bekaroǧlu, Özer

PY - 2000

Y1 - 2000

N2 - Unsymmetric metallophthalocyanines (M = Zn, Co, Ni) carrying alkylthio and acetyl-oxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The extremely soluble compounds were characterized by their IR, 1H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.

AB - Unsymmetric metallophthalocyanines (M = Zn, Co, Ni) carrying alkylthio and acetyl-oxyethylthio groups on peripheral positions were prepared from 4,5-bis-alkylthio-phthalonitrile, 4,5-bis-(acetyloxyethylthio)-phthalonitrile, and the corresponding anhydrous metal salts Zn(CH3COO)2, NiCl2, and CoCl2. The extremely soluble compounds were characterized by their IR, 1H NMR, and UV/Vis spectra. Their long wavelength absorption band was found to be bathochromically shifted; their solubility is superior to that of symmetrical phthalocyanines.

KW - Alkylthio derivatives

KW - Phthalocyanines

KW - Unsymmetrical substituents

UR - https://www.scopus.com/pages/publications/0039592575

U2 - 10.1007/s007060070104

DO - 10.1007/s007060070104

M3 - Article

AN - SCOPUS:0039592575

SN - 0026-9247

VL - 131

SP - 287

EP - 292

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 3

ER -

Synthesis and characterization of new unsymmetrically substituted phthalocyanines

Özet

Belgeye Erişim

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