Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

Ozan Sanli Senturk; Sema Sert; Ümmuhan Özdemir

doi:10.1515/znb-2003-1115

Synthesis and Characterization of Metal Carbonyls [M(CO)₆(M = Cr, Mo, W), Re(CO)₅Br, Mn(CO)₃Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

Ozan Sanli Senturk^*
, Sema Sert
, Ümmuhan Özdemir

^*Bu çalışma için yazışmadan sorumlu yazar

Ege University
National Research Council of Canada
Gazi University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

30 Atıf (Scopus)

Özet

Five new complexes, M(CO)₅(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)₄Br(nafesh) (4) and Mn(CO)₃ (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)₆ (M = Cr, Mo, W), Re(CO)₅Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, ¹H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) ₅(nafesh) (M = Cr, Mo, W) and Re(CO)₄Br(nafesh) and as tridentate ligand in Mn(CO)₃(nafesh).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1124-1127
Sayfa sayısı	4
Dergi	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Hacim	58
Basın numarası	11
DOI'lar	https://doi.org/10.1515/znb-2003-1115
Yayın durumu	Yayınlandı - Kas 2003
Harici olarak yayınlandı	Evet

Finansman

This research was supported by Gazi University Research Found under Project No 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUB˙TAK for allocation of time at the NMR, mass spectra and elemental analyses.

Finansörler	Finansör numarası
Gazi University Research Found	05-98/24

Belgeye Erişim

10.1515/znb-2003-1115

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{2b342b74e52c4e0cb6d3517107a5a61e,

title = "Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)",

abstract = "Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3 (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) 5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).",

keywords = "2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone, Hydrazone, Metal carbonyls",

author = "Senturk, \{Ozan Sanli\} and Sema Sert and {\"U}mmuhan {\"O}zdemir",

year = "2003",

month = nov,

doi = "10.1515/znb-2003-1115",

language = "English",

volume = "58",

pages = "1124--1127",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "11",

}

Synthesis and Characterization of Metal Carbonyls [M(CO)₆(M = Cr, Mo, W), Re(CO)₅Br, Mn(CO)₃Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh). / Senturk, Ozan Sanli; Sert, Sema; Özdemir, Ümmuhan.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Hac. 58, No. 11, 11.2003, p. 1124-1127.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone (nafesh)

AU - Senturk, Ozan Sanli

AU - Sert, Sema

AU - Özdemir, Ümmuhan

PY - 2003/11

Y1 - 2003/11

N2 - Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3 (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) 5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).

AB - Five new complexes, M(CO)5(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)4Br(nafesh) (4) and Mn(CO)3 (nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M = Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with 2-hydroxy-1- napthaldehyde ethanesulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, 1H NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO) 5(nafesh) (M = Cr, Mo, W) and Re(CO)4Br(nafesh) and as tridentate ligand in Mn(CO)3(nafesh).

KW - 2-Hydroxy-1-napthaldehyde Ethanesulfonylhydrazone

KW - Hydrazone

KW - Metal carbonyls

UR - https://www.scopus.com/pages/publications/1642560874

U2 - 10.1515/znb-2003-1115

DO - 10.1515/znb-2003-1115

M3 - Article

AN - SCOPUS:1642560874

SN - 0932-0776

VL - 58

SP - 1124

EP - 1127

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

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