Synthesis and characterization of metal carbonyl complexes of M(CO) 6 (M = Cr, Mo, and W), Re(CO)5Br, and Mn(CO)3Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

Ümmühan Özdemir; Nurcan Karacan; Ozan Sanli Şentürk; Sema Sert; Fadime Uǧur

doi:10.1081/SIM-120037527

Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

Ümmühan Özdemir
, Nurcan Karacan
, Ozan Sanli Şentürk^*
, Sema Sert
, Fadime Uǧur

^*Bu çalışma için yazışmadan sorumlu yazar

Gazi University
Ege University
National Research Council of Canada

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

24 Atıf (Scopus)

Özet

Ten new complexes, [M(CO)₅(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)₄Br(amsh)] (4a), and [Mn(CO)₂(amsh)Cp] (5a) and [M(CO)₅ (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) ₄Br(msh)], (4b), and [Mn(CO)₃(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) ₆] (M = Cr, Mo, and W), [Re(CO)₅Br], and [Mn(CO) ₃Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and ¹H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1057-1067
Sayfa sayısı	11
Dergi	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Hacim	34
Basın numarası	6
DOI'lar	https://doi.org/10.1081/SIM-120037527
Yayın durumu	Yayınlandı - Haz 2004
Harici olarak yayınlandı	Evet

Finansman

We thank BP (Turkey) for the provision of the photochemical apparatus and the Research Foundation of Ege and Gazi University for funds. We thank TUBİTAK for allocation of time at the NMR, mass spectra and elemental analyses.

Finansörler
Research Foundation of Ege and Gazi University
BP

Belgeye Erişim

10.1081/SIM-120037527

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

Özdemir, Ü., Karacan, N., Şentürk, O. S., Sert, S., & Uǧur, F. (2004). Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 34(6), 1057-1067. https://doi.org/10.1081/SIM-120037527

Özdemir, Ümmühan ; Karacan, Nurcan ; Şentürk, Ozan Sanli et al. / Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2004 ; Hac. 34, No. 6. pp. 1057-1067.

@article{d842f36c4e734eb6baefb0fe0742f3f8,

title = "Synthesis and characterization of metal carbonyl complexes of M(CO) 6 (M = Cr, Mo, and W), Re(CO)5Br, and Mn(CO)3Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)",

abstract = "Ten new complexes, [M(CO)5(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)4Br(amsh)] (4a), and [Mn(CO)2(amsh)Cp] (5a) and [M(CO)5 (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) 4Br(msh)], (4b), and [Mn(CO)3(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) 6] (M = Cr, Mo, and W), [Re(CO)5Br], and [Mn(CO) 3Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).",

keywords = "Metal carbonyl complexes, Methanesulfonylhydrazone, Monodentate ligands, Schiff base",

author = "{\"U}mm{\"u}han {\"O}zdemir and Nurcan Karacan and {\c S}ent{\"u}rk, \{Ozan Sanli\} and Sema Sert and Fadime Uǧur",

year = "2004",

month = jun,

doi = "10.1081/SIM-120037527",

language = "English",

volume = "34",

pages = "1057--1067",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

issn = "0094-5714",

number = "6",

}

Özdemir, Ü, Karacan, N, Şentürk, OS, Sert, S & Uǧur, F 2004, 'Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)', Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, hac. 34, no. 6, pp. 1057-1067. https://doi.org/10.1081/SIM-120037527

Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). / Özdemir, Ümmühan; Karacan, Nurcan; Şentürk, Ozan Sanli et al.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Hac. 34, No. 6, 06.2004, p. 1057-1067.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Synthesis and characterization of metal carbonyl complexes of M(CO) 6 (M = Cr, Mo, and W), Re(CO)5Br, and Mn(CO)3Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh)

AU - Özdemir, Ümmühan

AU - Karacan, Nurcan

AU - Şentürk, Ozan Sanli

AU - Sert, Sema

AU - Uǧur, Fadime

PY - 2004/6

Y1 - 2004/6

N2 - Ten new complexes, [M(CO)5(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)4Br(amsh)] (4a), and [Mn(CO)2(amsh)Cp] (5a) and [M(CO)5 (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) 4Br(msh)], (4b), and [Mn(CO)3(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) 6] (M = Cr, Mo, and W), [Re(CO)5Br], and [Mn(CO) 3Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

AB - Ten new complexes, [M(CO)5(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)4Br(amsh)] (4a), and [Mn(CO)2(amsh)Cp] (5a) and [M(CO)5 (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO) 4Br(msh)], (4b), and [Mn(CO)3(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO) 6] (M = Cr, Mo, and W), [Re(CO)5Br], and [Mn(CO) 3Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

KW - Metal carbonyl complexes

KW - Methanesulfonylhydrazone

KW - Monodentate ligands

KW - Schiff base

UR - https://www.scopus.com/pages/publications/3242779293

U2 - 10.1081/SIM-120037527

DO - 10.1081/SIM-120037527

M3 - Article

AN - SCOPUS:3242779293

SN - 0094-5714

VL - 34

SP - 1057

EP - 1067

JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 6

ER -

Özdemir Ü, Karacan N, Şentürk OS, Sert S, Uǧur F. Synthesis and characterization of metal carbonyl complexes of M(CO) ₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with acetonemethanesulfonylhydrazone (amsh) and methanesulfonylhydrazone (msh). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 2004 Haz;34(6):1057-1067. doi: 10.1081/SIM-120037527