Synthesis and characterization of boron-acrylate/Santa Barbara Amorphous-15 polymer composite

Nargiz Aliyeva; Tuba Cakir Canak; İbrahim Ersin Serhatlı

doi:10.1002/app.50445

Synthesis and characterization of boron-acrylate/Santa Barbara Amorphous-15 polymer composite

Nargiz Aliyeva
, Tuba Cakir Canak
, İbrahim Ersin Serhatlı^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

5 Atıf (Scopus)

Özet

In the present work, boron-acrylate/Santa Barbara Amorphous (SBA)-15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA-15 was functionalized with 3-(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA-15 surface. The structural analysis was evaluated via Fourier-transform infrared spectroscopy and solid-state nuclear magnetic resonance ¹³C. Samples were also characterized by using scanning electron microscopy, X-ray powder diffraction, N₂ adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron-acrylate/SBA-15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.

Orijinal dil	İngilizce
Makale numarası	50445
Dergi	Journal of Applied Polymer Science
Hacim	138
Basın numarası	20
DOI'lar	https://doi.org/10.1002/app.50445
Yayın durumu	Yayınlandı - 20 May 2021

Bibliyografik not

Publisher Copyright:
© 2021 Wiley Periodicals LLC.

Finansman

This work was supported and funded by Research Fund of the Istanbul Teknik Üniversitesi (ITU‐BAP, Project Number: TYL‐2019‐42179). This work was supported and funded by Research Fund of the Istanbul Teknik ?niversitesi (ITU-BAP, Project Number: TYL-2019-42179).

Finansörler	Finansör numarası
ITU-BAP
Istanbul Teknik ?
Istanbul Teknik Üniversitesi	TYL‐2019‐42179

Belgeye Erişim

10.1002/app.50445

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{83153462518543bd85f686862378ac0c,

title = "Synthesis and characterization of boron-acrylate/Santa Barbara Amorphous-15 polymer composite",

abstract = "In the present work, boron-acrylate/Santa Barbara Amorphous (SBA)-15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA-15 was functionalized with 3-(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA-15 surface. The structural analysis was evaluated via Fourier-transform infrared spectroscopy and solid-state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X-ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron-acrylate/SBA-15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.",

keywords = "SBA-15, boron acrylate, mesoporous silica, mesoporous silica/polymer composite",

author = "Nargiz Aliyeva and Canak, \{Tuba Cakir\} and Serhatlı, \{İbrahim Ersin\}",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley Periodicals LLC.",

year = "2021",

month = may,

day = "20",

doi = "10.1002/app.50445",

language = "English",

volume = "138",

journal = "Journal of Applied Polymer Science",

issn = "0021-8995",

publisher = "John Wiley \& Sons Inc.",

number = "20",

}

TY - JOUR

T1 - Synthesis and characterization of boron-acrylate/Santa Barbara Amorphous-15 polymer composite

AU - Aliyeva, Nargiz

AU - Canak, Tuba Cakir

AU - Serhatlı, İbrahim Ersin

PY - 2021/5/20

Y1 - 2021/5/20

N2 - In the present work, boron-acrylate/Santa Barbara Amorphous (SBA)-15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA-15 was functionalized with 3-(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA-15 surface. The structural analysis was evaluated via Fourier-transform infrared spectroscopy and solid-state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X-ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron-acrylate/SBA-15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.

AB - In the present work, boron-acrylate/Santa Barbara Amorphous (SBA)-15 polymer composite was synthesized using free radical polymerization method. Firstly, SBA-15 was functionalized with 3-(trimethoxysilyl)propyl methacrylate to obtain chemically bonded boron acrylate (BAc) polymer on the SBA-15 surface. The structural analysis was evaluated via Fourier-transform infrared spectroscopy and solid-state nuclear magnetic resonance 13C. Samples were also characterized by using scanning electron microscopy, X-ray powder diffraction, N2 adsorption/desorption and thermogravimetric analysis. In order to examine the BAc polymers in the mesopores, the silica framework was removed via hydrofluoric acid etching process. The results indicated that the synthesis of boron-acrylate/SBA-15 polymer composite was performed successfully. Thermal stabilities of the composites were higher with greater amounts of BAc polymer in mesopores under oxidative conditions.

KW - SBA-15

KW - boron acrylate

KW - mesoporous silica

KW - mesoporous silica/polymer composite

UR - https://www.scopus.com/pages/publications/85099193595

U2 - 10.1002/app.50445

DO - 10.1002/app.50445

M3 - Article

AN - SCOPUS:85099193595

SN - 0021-8995

VL - 138

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 20

M1 - 50445

ER -

Synthesis and characterization of boron-acrylate/Santa Barbara Amorphous-15 polymer composite

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

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