Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

Halit Koçan; Ayfer Kalkan Burat

doi:10.1007/s00706-012-0790-9

Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

Halit Koçan
, Ayfer Kalkan Burat^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

21 Atıf (Scopus)

Özet

The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, ¹H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	171-177
Sayfa sayısı	7
Dergi	Monatshefte fur Chemie
Hacim	144
Basın numarası	2
DOI'lar	https://doi.org/10.1007/s00706-012-0790-9
Yayın durumu	Yayınlandı - Şub 2013

Finansman

This work was supported by the Research Fund of the Technical University of Istanbul (project no: 33434) and TUBITAK (project no: 110T800).

Finansörler	Finansör numarası
TUBITAK	110T800
Istanbul Teknik Üniversitesi	33434

Belgeye Erişim

10.1007/s00706-012-0790-9

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines",

abstract = "The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.",

keywords = "Aggregation, Isomers, Manganese, Phthalocyanines, Solubility",

author = "Halit Ko{\c c}an and Burat, \{Ayfer Kalkan\}",

year = "2013",

month = feb,

doi = "10.1007/s00706-012-0790-9",

language = "English",

volume = "144",

pages = "171--177",

journal = "Monatshefte fur Chemie",

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T1 - Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

AU - Koçan, Halit

AU - Burat, Ayfer Kalkan

PY - 2013/2

Y1 - 2013/2

N2 - The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

AB - The synthesis of novel, symmetrical, tetrasubstituted metal-free and metallo-phthalocyanines (zinc, cobalt, manganese, indium) bearing four [7-(trifluoromethyl)quinolin-4-yl]oxy units has been reported. The new compounds were characterized using UV-Vis, IR, 1H NMR, and mass spectroscopic data. The wavelength of the Q band is related to the metal coordinated at the center of the phthalocyanine rings and follows the order Mn > In > Zn > Co. The phthalocyanines displayed good solubility in organic solvents such as chloroform, tetrahydrofuran, dimethylformamide, dimethylsulfoxide, and toluene.

KW - Aggregation

KW - Isomers

KW - Manganese

KW - Phthalocyanines

KW - Solubility

UR - https://www.scopus.com/pages/publications/84878560623

U2 - 10.1007/s00706-012-0790-9

DO - 10.1007/s00706-012-0790-9

M3 - Article

AN - SCOPUS:84878560623

SN - 0026-9247

VL - 144

SP - 171

EP - 177

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 2

ER -

Synthesis and characterization of [7-(trifluoromethyl)quinolin-4-yl]oxy- substituted phthalocyanines

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap