Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

H. Çatalgil-Giz; N. Uyanik; C. Erbil

doi:10.1016/0032-3861(92)90747-K

Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

H. Çatalgil-Giz^*
, N. Uyanik
, C. Erbil

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

17 Atıf (Scopus)

Özet

Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tüdos and Fineman-Ross methods. The reactivity ratios were found to be r_AMA = 2.35, r_BMA = 0.08 (Kelen-Tüdos) and r_AMA = 2.37, r_BMA = 0.08 (Fineman-Ross).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	655-656
Sayfa sayısı	2
Dergi	Polymer
Hacim	33
Basın numarası	3
DOI'lar	https://doi.org/10.1016/0032-3861(92)90747-K
Yayın durumu	Yayınlandı - 1992

Belgeye Erişim

10.1016/0032-3861(92)90747-K

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{98d69686d9d84c00a39c15e1ad34b241,

title = "Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate",

abstract = "Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-T{\"u}dos and Fineman-Ross methods. The reactivity ratios were found to be rAMA = 2.35, rBMA = 0.08 (Kelen-T{\"u}dos) and rAMA = 2.37, rBMA = 0.08 (Fineman-Ross).",

keywords = "Fineman-Ross method, group transfer polymerization, Kelen-T{\"u}dos method, reactivity ratio, statistical copolymerization",

author = "H. {\c C}atalgil-Giz and N. Uyanik and C. Erbil",

year = "1992",

doi = "10.1016/0032-3861(92)90747-K",

language = "English",

volume = "33",

pages = "655--656",

journal = "Polymer",

issn = "0032-3861",

number = "3",

}

TY - JOUR

T1 - Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

AU - Çatalgil-Giz, H.

AU - Uyanik, N.

AU - Erbil, C.

PY - 1992

Y1 - 1992

N2 - Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tüdos and Fineman-Ross methods. The reactivity ratios were found to be rAMA = 2.35, rBMA = 0.08 (Kelen-Tüdos) and rAMA = 2.37, rBMA = 0.08 (Fineman-Ross).

AB - Statistical copolymerizations have been performed for allyl methacrylate-butyl methacrylate systems using 1-methoxy-2-methyl-1-trimethylsilyloxypropene (initiator) and tris (dimethylamino) sulphonium bifluoride (catalyst) in tetrahydrofuran solution. Soluble allyl copolymers have been obtained by this method. The copolymer compositions were determined by ultraviolet spectroscopy and the results evaluated by the Kelen-Tüdos and Fineman-Ross methods. The reactivity ratios were found to be rAMA = 2.35, rBMA = 0.08 (Kelen-Tüdos) and rAMA = 2.37, rBMA = 0.08 (Fineman-Ross).

KW - Fineman-Ross method

KW - group transfer polymerization

KW - Kelen-Tüdos method

KW - reactivity ratio

KW - statistical copolymerization

UR - https://www.scopus.com/pages/publications/0042172153

U2 - 10.1016/0032-3861(92)90747-K

DO - 10.1016/0032-3861(92)90747-K

M3 - Article

AN - SCOPUS:0042172153

SN - 0032-3861

VL - 33

SP - 655

EP - 656

JO - Polymer

JF - Polymer

IS - 3

ER -

Statistical group transfer copolymerization. Monomer reactivity ratios for allyl methacrylate and n-butyl methacrylate

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap