Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

Hamdi Temel; Hüseyin Alp; Salih Ilhan; Berrin ZiyadanoǧullarI; Ismail YIlmaz

doi:10.1007/s00706-007-0713-3

Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

Hamdi Temel^*
, Hüseyin Alp
, Salih Ilhan
, Berrin ZiyadanoǧullarI
, Ismail YIlmaz

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Dicle University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

35 Atıf (Scopus)

Özet

La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, ¹H NMR, ¹³C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu²⁺ and Ni²⁺ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1199-1209
Sayfa sayısı	11
Dergi	Monatshefte fur Chemie
Hacim	138
Basın numarası	12
DOI'lar	https://doi.org/10.1007/s00706-007-0713-3
Yayın durumu	Yayınlandı - Ara 2007

Belgeye Erişim

10.1007/s00706-007-0713-3

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Parmak izi

Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

Alıntı Yap

Temel, H., Alp, H., Ilhan, S., ZiyadanoǧullarI, B., & YIlmaz, I. (2007). Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations. Monatshefte fur Chemie, 138(12), 1199-1209. https://doi.org/10.1007/s00706-007-0713-3

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title = "Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations",

abstract = "La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, 1H NMR, 13C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.",

keywords = "Electrochemical studies, Extraction, Thio Schiff base, Transition metal complexes",

author = "Hamdi Temel and H{\"u}seyin Alp and Salih Ilhan and Berrin ZiyadanoǧullarI and Ismail YIlmaz",

year = "2007",

month = dec,

doi = "10.1007/s00706-007-0713-3",

language = "English",

volume = "138",

pages = "1199--1209",

journal = "Monatshefte fur Chemie",

issn = "0026-9247",

publisher = "Springer",

number = "12",

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Temel, H, Alp, H, Ilhan, S, ZiyadanoǧullarI, B & YIlmaz, I 2007, 'Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations', Monatshefte fur Chemie, hac. 138, no. 12, pp. 1199-1209. https://doi.org/10.1007/s00706-007-0713-3

Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations. / Temel, Hamdi; Alp, Hüseyin; Ilhan, Salih et al.
In: Monatshefte fur Chemie, Hac. 138, No. 12, 12.2007, p. 1199-1209.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations

AU - Temel, Hamdi

AU - Alp, Hüseyin

AU - Ilhan, Salih

AU - ZiyadanoǧullarI, Berrin

AU - YIlmaz, Ismail

PY - 2007/12

Y1 - 2007/12

N2 - La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, 1H NMR, 13C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.

AB - La(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, 1H NMR, 13C NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.

KW - Electrochemical studies

KW - Extraction

KW - Thio Schiff base

KW - Transition metal complexes

UR - https://www.scopus.com/pages/publications/36749079826

U2 - 10.1007/s00706-007-0713-3

DO - 10.1007/s00706-007-0713-3

M3 - Article

AN - SCOPUS:36749079826

SN - 0026-9247

VL - 138

SP - 1199

EP - 1209

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 12

ER -

Temel H, Alp H, Ilhan S, ZiyadanoǧullarI B, YIlmaz I. Spectroscopic and electrochemical studies of transition metal complexes with N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7- trioxaheptane and structure effects on extractability of ligand towards some divalent cations. Monatshefte fur Chemie. 2007 Ara;138(12):1199-1209. doi: 10.1007/s00706-007-0713-3