Özet
4-Methoxy-2,6-bis(hydroxymethyl)phenol (1) was prepared from the reaction of 4-methoxyphenol and formaldehyde. The compound (1) was then oxidized to the 4-methoxy-2,6-diformylphenol (2) compound. Molecular structure of compound (2) was determined by X-ray diffraction method. A new symmetric porphyrin Schiff base ligand 4-methoxy-2,6-bis[5-(4-iminophenyl)-10,15,20-triphenylporphyrin]phenol (L) was prepared from the reaction of the 5-(4-aminophenyl)-10,15,20-triphenylporphyrin (TTP-NH2) and the compound (2) in the toluene solution. The metal complexes (Cu(II), Fe(III), Mn(III), Pt(II) and Zn(II)) of the ligand (L) were synthesized and characterized by the spectroscopic and analytical methods. The DNA (fish sperm FSdsDNA) binding studies of the ligand and its complexes were performed using UV-vis spectroscopy. Additionally, superoxide dismutase activities of the porphyrin Schiff base metal complexes were investigated. Additionally, electrochemical, photoluminescence and thermal properties of the compounds were investigated.
Orijinal dil | İngilizce |
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Sayfa (başlangıç-bitiş) | 821-838 |
Sayfa sayısı | 18 |
Dergi | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy |
Hacim | 151 |
DOI'lar | |
Yayın durumu | Yayınlandı - 13 Tem 2015 |
Harici olarak yayınlandı | Evet |
Bibliyografik not
Publisher Copyright:© 2015 Elsevier B.V. All rights reserved.
Finansman
We are grateful to The Scientific & Technological Research Council of Turkey (TUBITAK) (Project number: 113Z907) for the support of this research. The authors are also grateful to the Department of Chemistry, Loughborough University for X-ray data collection.
Finansörler | Finansör numarası |
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TUBITAK | 113Z907 |
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu |