Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives

Olcay Anac; Ayse Daut

doi:10.1002/jlac.199719970630

Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives

Olcay Anac^*
, Ayse Daut

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

34 Atıf (Scopus)

Özet

Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1249-1254
Sayfa sayısı	6
Dergi	Liebigs Annales
Basın numarası	6
DOI'lar	https://doi.org/10.1002/jlac.199719970630
Yayın durumu	Yayınlandı - 1997

Belgeye Erişim

10.1002/jlac.199719970630

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{561f789795724217a78b3e75d3962613,

title = "Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives",

abstract = "Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.",

keywords = "Carbenes, Carbonyl ylides, Chirality, Diazo compounds, α,β-Enones",

author = "Olcay Anac and Ayse Daut",

year = "1997",

doi = "10.1002/jlac.199719970630",

language = "English",

pages = "1249--1254",

journal = "Liebigs Annales",

issn = "0947-3440",

publisher = "Wiley-VCH Verlag",

number = "6",

}

TY - JOUR

T1 - Reactions of α,β-enones with diazo compounds, 2

T2 - Synthesis of dihydrofuran derivatives

AU - Anac, Olcay

AU - Daut, Ayse

PY - 1997

Y1 - 1997

N2 - Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.

AB - Several α,β-unsaturated ketones were treated with dimethyl diazomalonate and ethyl acetodiazoacetate under bis(acetylacetonato)copper(II) catalysis. Dihydrofuran derivatives, obviously arising from carbonyl ylides, were isolated in high yields. Structural identifications were carried out using 2D-NMR-spectroscopic data.

KW - Carbenes

KW - Carbonyl ylides

KW - Chirality

KW - Diazo compounds

KW - α,β-Enones

UR - https://www.scopus.com/pages/publications/33748827140

U2 - 10.1002/jlac.199719970630

DO - 10.1002/jlac.199719970630

M3 - Article

AN - SCOPUS:33748827140

SN - 0947-3440

SP - 1249

EP - 1254

JO - Liebigs Annales

JF - Liebigs Annales

IS - 6

ER -

Reactions of α,β-enones with diazo compounds, 2: Synthesis of dihydrofuran derivatives

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

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