Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

Ü Özdemir; O. S. Şentürk; S. Sert; N. Karacan; F. Uǧur

doi:10.1080/00958970600663880

Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

Ü Özdemir^*
, O. S. Şentürk
, S. Sert
, N. Karacan
, F. Uǧur

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Gazi University
Ege University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

31 Atıf (Scopus)

Özet

Five new complexes, [M(CO)₅(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)₄Br(nafmsh)], 4 and [Mn(CO)₃(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)₆] (M = Cr, Mo, W), [Re(CO)₅Br], and [Mn(CO)₃Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and ¹H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1905-1911
Sayfa sayısı	7
Dergi	Journal of Coordination Chemistry
Hacim	59
Basın numarası	17
DOI'lar	https://doi.org/10.1080/00958970600663880
Yayın durumu	Yayınlandı - 20 Kas 2006

Finansman

This research was supported by Gazi University Research Fund under Project No. 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUBITAK_ for allocation of time at the NMR, mass spectra and elemental analyses.

Finansörler	Finansör numarası
Gazi University Research Fund	05-98/24

Belgeye Erişim

10.1080/00958970600663880

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{6809fbf6d903491e9a1c3086ad66f103,

title = "Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products",

abstract = "Five new complexes, [M(CO)5(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)4Br(nafmsh)], 4 and [Mn(CO)3(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and 1H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.",

keywords = "Metal carbonyls, Cyclopentadienyl, Methanesulfonylhydrazone, Photosubstitution",

author = "{\"U} {\"O}zdemir and {\c S}ent{\"u}rk, \{O. S.\} and S. Sert and N. Karacan and F. Uǧur",

year = "2006",

month = nov,

day = "20",

doi = "10.1080/00958970600663880",

language = "English",

volume = "59",

pages = "1905--1911",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "17",

}

TY - JOUR

T1 - Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

AU - Özdemir, Ü

AU - Şentürk, O. S.

AU - Sert, S.

AU - Karacan, N.

AU - Uǧur, F.

PY - 2006/11/20

Y1 - 2006/11/20

N2 - Five new complexes, [M(CO)5(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)4Br(nafmsh)], 4 and [Mn(CO)3(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and 1H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

AB - Five new complexes, [M(CO)5(nafmsh)] [M = Cr, 1; Mo, 2; W, 3], [Re(CO)4Br(nafmsh)], 4 and [Mn(CO)3(nafmsh)], 5 have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo, W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxy-1-naphthaldehyde methanesulfonylhydrazone (nafmsh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR, and 1H NMR spectroscopy. The spectroscopic studies show nafmsh is a monodentate ligand coordinating via the imine N donor atom in 1-4 and as a tridentate ligand in 5.

KW - Metal carbonyls, Cyclopentadienyl

KW - Methanesulfonylhydrazone

KW - Photosubstitution

UR - https://www.scopus.com/pages/publications/33750412193

U2 - 10.1080/00958970600663880

DO - 10.1080/00958970600663880

M3 - Article

AN - SCOPUS:33750412193

SN - 0095-8972

VL - 59

SP - 1905

EP - 1911

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 17

ER -

Reaction of metal carbonyls with 2-hydroxy-1-naphthaldeyde methanesulfonylhydrazone and characterization of the substitution products

Özet

Finansman

Belgeye Erişim

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