Quantitative conversion of poly(acrylamide) into poly(vinylamine) by a modified Hofmann degradation

Niyazi Biçak; A. Sezai Saraç; Güneş Koza; Tülay Atay; Filiz Şekal

doi:10.1016/0923-1137(93)90060-S

Quantitative conversion of poly(acrylamide) into poly(vinylamine) by a modified Hofmann degradation

Niyazi Biçak^*
, A. Sezai Saraç
, Güneş Koza
, Tülay Atay
, Filiz Şekal

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

9 Atıf (Scopus)

Özet

Very high molecular weight poly(vinylamine) was prepared by a modified Hofmann rearrangement of poly(acrylamide). The reaction was carried out in ethylene glycol using the monosodium salt of this solvent and bromine instead of sodium hypohalogenides in the original Hofmann rearrangement. Poly(vinyl 2-hydroxyethylurethane) was formed as an intermediate product. Hydrolysis of the latter gave poly(vinylamine) with quantitative conversions.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	135-139
Sayfa sayısı	5
Dergi	Reactive Polymers
Hacim	21
Basın numarası	1-2
DOI'lar	https://doi.org/10.1016/0923-1137(93)90060-S
Yayın durumu	Yayınlandı - Eki 1993

Belgeye Erişim

10.1016/0923-1137(93)90060-S

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Quantitative conversion of poly(acrylamide) into poly(vinylamine) by a modified Hofmann degradation",

abstract = "Very high molecular weight poly(vinylamine) was prepared by a modified Hofmann rearrangement of poly(acrylamide). The reaction was carried out in ethylene glycol using the monosodium salt of this solvent and bromine instead of sodium hypohalogenides in the original Hofmann rearrangement. Poly(vinyl 2-hydroxyethylurethane) was formed as an intermediate product. Hydrolysis of the latter gave poly(vinylamine) with quantitative conversions.",

keywords = "Hofmann degradation of poly(acrylamide), poly(vinyl 2-hydroxyethylurethane), preparation of poly(vinylamine)",

author = "Niyazi Bi{\c c}ak and \{Sezai Sara{\c c}\}, A. and G{\"u}ne{\c s} Koza and T{\"u}lay Atay and Filiz {\c S}ekal",

year = "1993",

month = oct,

doi = "10.1016/0923-1137(93)90060-S",

language = "English",

volume = "21",

pages = "135--139",

journal = "Reactive Polymers",

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TY - JOUR

T1 - Quantitative conversion of poly(acrylamide) into poly(vinylamine) by a modified Hofmann degradation

AU - Biçak, Niyazi

AU - Sezai Saraç, A.

AU - Koza, Güneş

AU - Atay, Tülay

AU - Şekal, Filiz

PY - 1993/10

Y1 - 1993/10

N2 - Very high molecular weight poly(vinylamine) was prepared by a modified Hofmann rearrangement of poly(acrylamide). The reaction was carried out in ethylene glycol using the monosodium salt of this solvent and bromine instead of sodium hypohalogenides in the original Hofmann rearrangement. Poly(vinyl 2-hydroxyethylurethane) was formed as an intermediate product. Hydrolysis of the latter gave poly(vinylamine) with quantitative conversions.

AB - Very high molecular weight poly(vinylamine) was prepared by a modified Hofmann rearrangement of poly(acrylamide). The reaction was carried out in ethylene glycol using the monosodium salt of this solvent and bromine instead of sodium hypohalogenides in the original Hofmann rearrangement. Poly(vinyl 2-hydroxyethylurethane) was formed as an intermediate product. Hydrolysis of the latter gave poly(vinylamine) with quantitative conversions.

KW - Hofmann degradation of poly(acrylamide)

KW - poly(vinyl 2-hydroxyethylurethane)

KW - preparation of poly(vinylamine)

UR - https://www.scopus.com/pages/publications/0027680537

U2 - 10.1016/0923-1137(93)90060-S

DO - 10.1016/0923-1137(93)90060-S

M3 - Article

AN - SCOPUS:0027680537

SN - 0923-1137

VL - 21

SP - 135

EP - 139

JO - Reactive Polymers

JF - Reactive Polymers

IS - 1-2

ER -

Quantitative conversion of poly(acrylamide) into poly(vinylamine) by a modified Hofmann degradation

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

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