Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

Fadime Uǧur; Ozan Sanli Şentürk; Işil Topaloǧlu

doi:10.1080/00945710009351862

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu)

Fadime Uǧur^*, Ozan Sanli Şentürk, Işil Topaloǧlu

^*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

8 Atıf (Scopus)

Özet

Co₂(CO)₈ and R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co₂(μ-CO)(μ₄-S)(CO)₄]₂, (1), [Co₄(CO)₉(μ3-S)(μ-PR₂)₂] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co₃(CO)₇(μ₃-S)(SPR₂)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and ³¹P-[¹H] NMR spectroscopy and mass spectrometry.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1697-1702
Sayfa sayısı	6
Dergi	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Hacim	30
Basın numarası	9
DOI'lar	https://doi.org/10.1080/00945710009351862
Yayın durumu	Yayınlandı - 2000
Harici olarak yayınlandı	Evet

Finansman

We thank TUBITAK and the Research Foundation of Ege University for funds and

Finansörler	Finansör numarası
Research Foundation of Ege University
TUBITAK

Belgeye Erişim

10.1080/00945710009351862

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{99f2550571f24d62b115558563104a41,

title = "Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)",

abstract = "Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.",

author = "Fadime Uǧur and {\c S}ent{\"u}rk, {Ozan Sanli} and I{\c s}il Topaloǧlu",

year = "2000",

doi = "10.1080/00945710009351862",

language = "English",

volume = "30",

pages = "1697--1702",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

issn = "0094-5714",

publisher = "Taylor and Francis Ltd.",

number = "9",

}

Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R₂P(S)P(S)R₂ (R = Me, Et, n-Pr, n-Bu). / Uǧur, Fadime; Şentürk, Ozan Sanli; Topaloǧlu, Işil.
In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Hac. 30, No. 9, 2000, p. 1697-1702.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

AU - Uǧur, Fadime

AU - Şentürk, Ozan Sanli

AU - Topaloǧlu, Işil

PY - 2000

Y1 - 2000

N2 - Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.

AB - Co2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(μ-CO)(μ4-S)(CO)4]2, (1), [Co4(CO)9(μ3-S)(μ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(μ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.

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M3 - Article

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