Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

Ayfer Kalkan Burat; Atif Koca; Jan P. Lewtak; Daniel T. Gryko

doi:10.1016/j.synthmet.2011.05.010

Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

Ayfer Kalkan Burat^*, Atif Koca, Jan P. Lewtak, Daniel T. Gryko

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

25 Atıf (Scopus)

Özet

The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, ¹H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1537-1545
Sayfa sayısı	9
Dergi	Synthetic Metals
Hacim	161
Basın numarası	15-16
DOI'lar	https://doi.org/10.1016/j.synthmet.2011.05.010
Yayın durumu	Yayınlandı - Ağu 2011

Finansman

This work was funded by Marie Curie Research Training Network ‘REVCAT’ (Contract Number: MRTN-CT-2006-035866 ).

Finansörler	Finansör numarası
Marie Curie Research Training Network	MRTN-CT-2006-035866

Belgeye Erişim

10.1016/j.synthmet.2011.05.010

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{e330191050ce4f198f205868eae9fc1b,

title = "Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents",

abstract = "The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, 1H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.",

keywords = "Electrochemistry, Phthalocyanine, Spectroelectrochemistry, Unsymmetric, Zinc",

author = "Burat, {Ayfer Kalkan} and Atif Koca and Lewtak, {Jan P.} and Gryko, {Daniel T.}",

year = "2011",

month = aug,

doi = "10.1016/j.synthmet.2011.05.010",

language = "English",

volume = "161",

pages = "1537--1545",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "15-16",

}

TY - JOUR

T1 - Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

AU - Burat, Ayfer Kalkan

AU - Koca, Atif

AU - Lewtak, Jan P.

AU - Gryko, Daniel T.

PY - 2011/8

Y1 - 2011/8

N2 - The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, 1H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.

AB - The synthesis of novel, unsymmetrical, octasubstituted metal-free and metallophthalocyanines (zinc, cobalt) bearing one chlorine, one morpholine moieties and six 4-tert-butylphenoxy substituents was achieved by a statistical condensation reaction of two corresponding phthalonitriles. The new compounds have been characterized by using elemental analyses, UV-vis, IR, 1H NMR and mass spectroscopic data. Voltammetric and spectroelectrochemical studies are in harmony with the reported metallophthalocyanine complexes, which support the proposed structure of the complexes.

KW - Electrochemistry

KW - Phthalocyanine

KW - Spectroelectrochemistry

KW - Unsymmetric

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=80051596389&partnerID=8YFLogxK

U2 - 10.1016/j.synthmet.2011.05.010

DO - 10.1016/j.synthmet.2011.05.010

M3 - Article

AN - SCOPUS:80051596389

SN - 0379-6779

VL - 161

SP - 1537

EP - 1545

JO - Synthetic Metals

JF - Synthetic Metals

IS - 15-16

ER -

Preparation, electrochemistry and optical properties of unsymmetrical phthalocyanines bearing morpholine and tert-butylphenoxy substituents

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap