Polytetrahydrofuran macroinimers - 3. Synthesis of polymethyl methacrylate with side chain block copolymers of tetrahydrofuran and methyl methacrylate

Yeşim Hepuzer, I. Ersin Serhatli, Yusuf Yaǧci*

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Araştırma sonucu: ???type-name???Makalebilirkişi

7 Atıf (Scopus)

Özet

Photoactive polytetrahydrofuran macroinimers were synthesized by the cationic polymerization of tetrahydrofuran initiated by the unsaturated oxocarbenium salt and subsequent termination by 2-picoline N-oxide. Macroinimers incorporating vinyl and pyridinium groups and methyl methacrylate were used in the grafting reaction in the presence of 2,2′-azobisisobutyronitrile as a thermal initiator. Side chain block copolymers were obtained by indirect photochemical polymerization of methyl methacrylate. Upon subjecting the pyridinium-ion-containing graft copolymer to UV irradiation in the presence of anthracene (photosensitizer) and methyl methacrylate, the polymerization of methyl methacrylate was initiated.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)631-636
Sayfa sayısı6
DergiEuropean Polymer Journal
Hacim34
Basın numarası5-6
Yayın durumuYayınlandı - May 1998

Parmak izi

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