Polymerization of Thienothiophenes and Dithienothiophenes via Click-Reaction for Electronic Applications

Ali Buyruk; M. Emin Cinar; Mehmet S. Eroglu; Turan Ozturk

doi:10.1002/slct.201600697

Polymerization of Thienothiophenes and Dithienothiophenes via Click-Reaction for Electronic Applications

Ali Buyruk
, M. Emin Cinar
, Mehmet S. Eroglu
, Turan Ozturk^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

13 Atıf (Scopus)

Özet

In this work, donor−acceptor (D−A) copolymers of thienothiophenes and dithienothiophenes, having 1,2,3-triazole units were prepared via a click reaction. Their optoelectronic properties were explored systematically providing the optical and electrochemical band gaps varying from 2.2 to 2.8 eV. Density functional theory (DFT) investigations of the model compounds revealed the presence of an intramolecular charge transfer transition between the donor TT/DTT units and 1,2,3-triazole acceptor group.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	3028-3032
Sayfa sayısı	5
Dergi	ChemistrySelect
Hacim	1
Basın numarası	12
DOI'lar	https://doi.org/10.1002/slct.201600697
Yayın durumu	Yayınlandı - 1 Ağu 2016

Bibliyografik not

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Finansman

We thank The Scientific and Technological Research Council of Turkey (TUBITAK) (113Z591), Istanbul Technical University (A. Buyruk, MSc) and Unsped Global Logistic for financial support. M. E. Cinar is grateful to TUBITAK for Postdoctoral Research Fellowships BIDEB 2216 program. We are indebted to National Center for High Performance Computing (UYBHM) (tvddvb) and the High-Performance-Computing (HPC) Linux Cluster HorUS of University of Siegen for the computer time provided.

Finansörler	Finansör numarası
İstanbul Teknik Üniversitesi
TUBITAK	113Z591
Unsped Global Logistic
National Council for Scientific Research

Belgeye Erişim

10.1002/slct.201600697

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Polymerization of Thienothiophenes and Dithienothiophenes via Click-Reaction for Electronic Applications",

abstract = "In this work, donor−acceptor (D−A) copolymers of thienothiophenes and dithienothiophenes, having 1,2,3-triazole units were prepared via a click reaction. Their optoelectronic properties were explored systematically providing the optical and electrochemical band gaps varying from 2.2 to 2.8 eV. Density functional theory (DFT) investigations of the model compounds revealed the presence of an intramolecular charge transfer transition between the donor TT/DTT units and 1,2,3-triazole acceptor group.",

keywords = "Click reaction, DFT, Dithienothiophene, Optoelectronic property, Thienothiophene",

author = "Ali Buyruk and Cinar, \{M. Emin\} and Eroglu, \{Mehmet S.\} and Turan Ozturk",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2016",

month = aug,

day = "1",

doi = "10.1002/slct.201600697",

language = "English",

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T1 - Polymerization of Thienothiophenes and Dithienothiophenes via Click-Reaction for Electronic Applications

AU - Buyruk, Ali

AU - Cinar, M. Emin

AU - Eroglu, Mehmet S.

AU - Ozturk, Turan

PY - 2016/8/1

Y1 - 2016/8/1

N2 - In this work, donor−acceptor (D−A) copolymers of thienothiophenes and dithienothiophenes, having 1,2,3-triazole units were prepared via a click reaction. Their optoelectronic properties were explored systematically providing the optical and electrochemical band gaps varying from 2.2 to 2.8 eV. Density functional theory (DFT) investigations of the model compounds revealed the presence of an intramolecular charge transfer transition between the donor TT/DTT units and 1,2,3-triazole acceptor group.

AB - In this work, donor−acceptor (D−A) copolymers of thienothiophenes and dithienothiophenes, having 1,2,3-triazole units were prepared via a click reaction. Their optoelectronic properties were explored systematically providing the optical and electrochemical band gaps varying from 2.2 to 2.8 eV. Density functional theory (DFT) investigations of the model compounds revealed the presence of an intramolecular charge transfer transition between the donor TT/DTT units and 1,2,3-triazole acceptor group.

KW - Click reaction

KW - DFT

KW - Dithienothiophene

KW - Optoelectronic property

KW - Thienothiophene

UR - https://www.scopus.com/pages/publications/85019768611

U2 - 10.1002/slct.201600697

DO - 10.1002/slct.201600697

M3 - Article

AN - SCOPUS:85019768611

SN - 2365-6549

VL - 1

SP - 3028

EP - 3032

JO - ChemistrySelect

JF - ChemistrySelect

IS - 12

ER -

Polymerization of Thienothiophenes and Dithienothiophenes via Click-Reaction for Electronic Applications

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

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