Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

Ümit Tunca; I. Ersin Serhatli; Yusuf Yağci

doi:10.1007/BF00718923

Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

Ümit Tunca
, I. Ersin Serhatli
, Yusuf Yağci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

43 Atıf (Scopus)

Özet

Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] ² ,[ACP] and [Ce(IV)] ^-1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	483-488
Sayfa sayısı	6
Dergi	Polymer Bulletin
Hacim	22
Basın numarası	5-6
DOI'lar	https://doi.org/10.1007/BF00718923
Yayın durumu	Yayınlandı - Ara 1989

Belgeye Erişim

10.1007/BF00718923

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)",

abstract = " Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] 2 ,[ACP] and [Ce(IV)] -1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.",

author = "{\"U}mit Tunca and \{Ersin Serhatli\}, I. and Yusuf Yağci",

year = "1989",

month = dec,

doi = "10.1007/BF00718923",

language = "English",

volume = "22",

pages = "483--488",

journal = "Polymer Bulletin",

issn = "0170-0839",

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TY - JOUR

T1 - Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

AU - Tunca, Ümit

AU - Ersin Serhatli, I.

AU - Yağci, Yusuf

PY - 1989/12

Y1 - 1989/12

N2 - Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] 2 ,[ACP] and [Ce(IV)] -1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

AB - Acrylamide was polymerized by eeric ion Ce (IV)-4,4′-azobis(4-cyano pentanol)(ACP) redox pair in aqueous nitric acid under nitrogen atmosphere. The rate of polymerization is proportional to [M] 2 ,[ACP] and [Ce(IV)] -1 . Termination mechanism which was exclusively linear offered one azo group per polymeric chain. The obtained polyacrylamide can be used as a water soluble initiator for vinyl polymerization.

UR - https://www.scopus.com/pages/publications/0024899665

U2 - 10.1007/BF00718923

DO - 10.1007/BF00718923

M3 - Article

AN - SCOPUS:0024899665

SN - 0170-0839

VL - 22

SP - 483

EP - 488

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 5-6

ER -

Polymerization of acrylamide initiated by the redox system Ce(IV)-4,4′-azobis (4-cyano pentanol)

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

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