Polymer grafting onto polyurethane backbone via Diels-Alder reaction

Soykan Agar, Hakan Durmaz, Ufuk Saim Gunay, Gurkan Hizal, Umit Tunca*

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12 Atıf (Scopus)

Özet

The aliphatic polyurethane with pendant anthracene moieties (PU-anthracene) was prepared from polycondensation of anthracen-9-yl methyl 3-hydroxy-2-(hydroxymethyl)-2-methylpropanoate (anthracene diol), 1 with hexamethylenediisocyanate in the presence of dibutyltindilaurate in CH2Cl2 at room temperature for 10 days. Thereafter, the PU-anthracene (Mn,GPC = 12,900 g/mol, Mw/Mn = 1.87, relative to PS standards) was clicked with a linear α-furan protected-maleimide terminated-poly(methyl methacrylate) (PMMA-MI) (Mn,GPC = 2500 g/mol, Mw/Mn = 1.33), or -poly(ethylene glycol) (PEG-MI) (Mn,GPC = 550 g/mol, Mw/Mn = 1.09), to result in well-defined PU-graft copolymers, PU-g-PMMA (Mn,GPC = 23800 g/mol, Mw/Mn = 1.65, relative to PS standards) or PU-g-PEG (Mn,GPC = 11,600 g/mol, Mw/Mn = 1.45, relative to PS standards) using Diels-Alder reaction in dioxane/toluene at 105 °C. The Diels-Alder grafting efficiencies were found to be over 93-99% using UV spectroscopy. Moreover, the structural analyses and the thermal transitions of all copolymers were determined via 1H NMR and DSC, respectively.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)521-527
Sayfa sayısı7
DergiJournal of Polymer Science, Part A: Polymer Chemistry
Hacim53
Basın numarası4
DOI'lar
Yayın durumuYayınlandı - 2 Ara 2014

Bibliyografik not

Publisher Copyright:
© 2014 Wiley Periodicals, Inc.

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