Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

Fatmanur Kasapoglu; Aysen Onen; Niyazi Bicak; Yusuf Yagci

doi:10.1016/S0032-3861(02)00029-0

Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

Fatmanur Kasapoglu
, Aysen Onen
, Niyazi Bicak
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

42 Atıf (Scopus)

Özet

A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	2575-2579
Sayfa sayısı	5
Dergi	Polymer
Hacim	43
Basın numarası	8
DOI'lar	https://doi.org/10.1016/S0032-3861(02)00029-0
Yayın durumu	Yayınlandı - 18 Şub 2002

Finansman

The authors would like to thank Istanbul Technical University, Research Fund and Turkish State Planning Association (DPT) for financial support.

Finansörler
DPT
Turkish State Planning Association
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1016/S0032-3861(02)00029-0

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Photoinitiated cationic polymerization using a novel phenacyl anilinium salt",

abstract = "A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.",

keywords = "Phenacyl anilinium salt, Photoinitiated cationic polymerization",

author = "Fatmanur Kasapoglu and Aysen Onen and Niyazi Bicak and Yusuf Yagci",

year = "2002",

month = feb,

day = "18",

doi = "10.1016/S0032-3861(02)00029-0",

language = "English",

volume = "43",

pages = "2575--2579",

journal = "Polymer",

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TY - JOUR

T1 - Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

AU - Kasapoglu, Fatmanur

AU - Onen, Aysen

AU - Bicak, Niyazi

AU - Yagci, Yusuf

PY - 2002/2/18

Y1 - 2002/2/18

N2 - A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.

AB - A novel phenacyl anilinium salt, N-phenacyl, N,N-dimethylanilinium hexafluoroantimonate, (PDA), has been synthesized and used as photoinitiator for cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinyl carbazol (NVC). Plausible mechanism of the photoinitiation involves the decay of the excited PDA with both heterolytic and homolytic cleavages of carbon-nitrogen bond. Thus, phenacylium cations formed directly or subsequent intermolecular electron transfer, respectively, initiate the polymerization.

KW - Phenacyl anilinium salt

KW - Photoinitiated cationic polymerization

UR - https://www.scopus.com/pages/publications/0037127989

U2 - 10.1016/S0032-3861(02)00029-0

DO - 10.1016/S0032-3861(02)00029-0

M3 - Article

AN - SCOPUS:0037127989

SN - 0032-3861

VL - 43

SP - 2575

EP - 2579

JO - Polymer

JF - Polymer

IS - 8

ER -

Photoinitiated cationic polymerization using a novel phenacyl anilinium salt

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap