Photoinduced crosslinking of polymers containing pendant hydroxyl groups by using bisbenzodioxinones

Volkan Kumbaraci, Naciye Talinli*, Yusuf Yagci

*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: Dergiye katkıMakalebilirkişi

28 Atıf (Scopus)

Özet

In the present study, it has been demonstrated that polymers containing pendant hydroxyl groups can undergo photoinduced crosslinking upon irradiation in the presence of bifunctional benzodioxinone. Irradiation of the copolymers of 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) in dichloromethane and THF solutions or in films containing bisbenzo-dioxinone, namely 5-[9-(4-oxo-2, 2-diphenyl-4H-benzo[d][1,3]dioxin-5-yloxy) nonyloxy]-2,2-diphenyl-4H-benzo[d][1,3]dioxin-4-one resulted in the formation of insoluble networks. Model studies using monofunctional napthodioxinone, namely 7-hydroxy-2,2- diphenyl-4H-naphtho[2,3-d][1,3]dioxin-4-one, revealed that cross-linking occurs via inter-chain ester formation between photochemically generated keten intermediates and pendant hydroxyl groups.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)72-77
Sayfa sayısı6
DergiMacromolecular Rapid Communications
Hacim28
Basın numarası1
DOI'lar
Yayın durumuYayınlandı - 5 Oca 2007

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