Photoinduced Controlled/Living Polymerizations

Cansu Aydogan; Gorkem Yilmaz; Ataulla Shegiwal; David M. Haddleton; Yusuf Yagci

doi:10.1002/anie.202117377

Photoinduced Controlled/Living Polymerizations

Cansu Aydogan
, Gorkem Yilmaz
, Ataulla Shegiwal
, David M. Haddleton^*
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
University of Warwick

Araştırma sonucu: Dergiye katkı › İnceleme makalesi › bilirkişi

141 Atıf (Scopus)

Özet

The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.

Orijinal dil	İngilizce
Makale numarası	e202117377
Dergi	Angewandte Chemie - International Edition
Hacim	61
Basın numarası	23
DOI'lar	https://doi.org/10.1002/anie.202117377
Yayın durumu	Yayınlandı - 7 Haz 2022

Bibliyografik not

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

Finansman

C.A. is grateful for the financial support from the Scientific and Technological Research Council of Turkey (TUBITAK, BIDEB‐2219 International Postdoctoral Research Scholarship Program). We would like to acknowledge the financial support from The Scientific and Technological Research Council of Turkey (Project Number: 120C121) and Istanbul Technical University Research Fund.

Finansörler	Finansör numarası
TUBITAK
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	120C121
Istanbul Teknik Üniversitesi

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

SKH 9 Sanayi, Yenilikçilik ve Altyapı

Belgeye Erişim

10.1002/anie.202117377

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{30d95ed144cb4337a9f6eecd71d48c19,

title = "Photoinduced Controlled/Living Polymerizations",

abstract = "The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.",

keywords = "Cationic Polymerization, Free-Radical Polymerization, Mechanistic Transformations, Photoinduced Controlled Living Polymerization",

author = "Cansu Aydogan and Gorkem Yilmaz and Ataulla Shegiwal and Haddleton, \{David M.\} and Yusuf Yagci",

note = "Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2022",

month = jun,

day = "7",

doi = "10.1002/anie.202117377",

language = "English",

volume = "61",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "23",

}

TY - JOUR

T1 - Photoinduced Controlled/Living Polymerizations

AU - Aydogan, Cansu

AU - Yilmaz, Gorkem

AU - Shegiwal, Ataulla

AU - Haddleton, David M.

AU - Yagci, Yusuf

PY - 2022/6/7

Y1 - 2022/6/7

N2 - The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.

AB - The application of photochemistry in polymer synthesis is of interest due to the unique possibilities offered compared to thermochemistry, including topological and temporal control, rapid polymerization, sustainable low-energy processes, and environmentally benign features leading to established and emerging applications in adhesives, coatings, adaptive manufacturing, etc. In particular, the utilization of photochemistry in controlled/living polymerizations often offers the capability for precise control over the macromolecular structure and chain length in addition to the associated advantages of photochemistry. Herein, the latest developments in photocontrolled living radical and cationic polymerizations and their combinations for application in polymer syntheses are discussed. This Review summarizes and highlights recent studies in the emerging area of photoinduced controlled/living polymerizations. A discussion of mechanistic details highlights differences as well as parallels between different systems for different polymerization methods and monomer applicability.

KW - Cationic Polymerization

KW - Free-Radical Polymerization

KW - Mechanistic Transformations

KW - Photoinduced Controlled Living Polymerization

UR - https://www.scopus.com/pages/publications/85128328938

U2 - 10.1002/anie.202117377

DO - 10.1002/anie.202117377

M3 - Review article

C2 - 35128771

AN - SCOPUS:85128328938

SN - 1433-7851

VL - 61

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

M1 - e202117377

ER -

Photoinduced Controlled/Living Polymerizations

Özet

Bibliyografik not

Finansman

BM SKH

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap