Photochemically masked benzophenone: Photoinitiated free radical polymerization by using benzodioxinone

Mehmet Atilla Tasdelen; Volkan Kumbaraci; Naciye Talinli; Yusuf Yagci

doi:10.1016/j.polymer.2006.09.020

Photochemically masked benzophenone: Photoinitiated free radical polymerization by using benzodioxinone

Mehmet Atilla Tasdelen
, Volkan Kumbaraci
, Naciye Talinli^*
, Yusuf Yagci

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

49 Atıf (Scopus)

Özet

A new photoinitiating system for free radical polymerization of methyl methacrylate (MMA) is reported. This system consists of benzodioxinone and hydrogen donors such as triethylamine (TEA), N,N-dimethyl ethanol amine (DMEA) and tetrahydrofuran (THF). A feasible mechanism involves photoinduced formation of benzophenone from benzodioxinone and subsequent hydrogen abstraction of photoexcited benzophenone from hydrogen donors to yield radicals capable of initiating polymerization of MMA.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	7611-7614
Sayfa sayısı	4
Dergi	Polymer
Hacim	47
Basın numarası	22
DOI'lar	https://doi.org/10.1016/j.polymer.2006.09.020
Yayın durumu	Yayınlandı - 18 Eki 2006

Finansman

The authors would like to thank Istanbul Technical University, Research Funds for the financial support. One of the authors (YY) would like to thank Turkish Academy of Sciences (TUBA) for its support.

Finansörler
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1016/j.polymer.2006.09.020

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Photochemically masked benzophenone: Photoinitiated free radical polymerization by using benzodioxinone",

abstract = "A new photoinitiating system for free radical polymerization of methyl methacrylate (MMA) is reported. This system consists of benzodioxinone and hydrogen donors such as triethylamine (TEA), N,N-dimethyl ethanol amine (DMEA) and tetrahydrofuran (THF). A feasible mechanism involves photoinduced formation of benzophenone from benzodioxinone and subsequent hydrogen abstraction of photoexcited benzophenone from hydrogen donors to yield radicals capable of initiating polymerization of MMA.",

keywords = "Benzodioxinone, Photolysis, Polymerization",

author = "Tasdelen, \{Mehmet Atilla\} and Volkan Kumbaraci and Naciye Talinli and Yusuf Yagci",

year = "2006",

month = oct,

day = "18",

doi = "10.1016/j.polymer.2006.09.020",

language = "English",

volume = "47",

pages = "7611--7614",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "22",

}

TY - JOUR

T1 - Photochemically masked benzophenone

T2 - Photoinitiated free radical polymerization by using benzodioxinone

AU - Tasdelen, Mehmet Atilla

AU - Kumbaraci, Volkan

AU - Talinli, Naciye

AU - Yagci, Yusuf

PY - 2006/10/18

Y1 - 2006/10/18

N2 - A new photoinitiating system for free radical polymerization of methyl methacrylate (MMA) is reported. This system consists of benzodioxinone and hydrogen donors such as triethylamine (TEA), N,N-dimethyl ethanol amine (DMEA) and tetrahydrofuran (THF). A feasible mechanism involves photoinduced formation of benzophenone from benzodioxinone and subsequent hydrogen abstraction of photoexcited benzophenone from hydrogen donors to yield radicals capable of initiating polymerization of MMA.

AB - A new photoinitiating system for free radical polymerization of methyl methacrylate (MMA) is reported. This system consists of benzodioxinone and hydrogen donors such as triethylamine (TEA), N,N-dimethyl ethanol amine (DMEA) and tetrahydrofuran (THF). A feasible mechanism involves photoinduced formation of benzophenone from benzodioxinone and subsequent hydrogen abstraction of photoexcited benzophenone from hydrogen donors to yield radicals capable of initiating polymerization of MMA.

KW - Benzodioxinone

KW - Photolysis

KW - Polymerization

UR - https://www.scopus.com/pages/publications/33749264814

U2 - 10.1016/j.polymer.2006.09.020

DO - 10.1016/j.polymer.2006.09.020

M3 - Article

AN - SCOPUS:33749264814

SN - 0032-3861

VL - 47

SP - 7611

EP - 7614

JO - Polymer

JF - Polymer

IS - 22

ER -

Photochemically masked benzophenone: Photoinitiated free radical polymerization by using benzodioxinone

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap