Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

Ozan Sanlı Şentürk; Fadime Ugˇur

doi:10.1081/SIM-100108266

Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

Ozan Sanlı Şentürk
, Fadime Ugˇur

Ege University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

30 Atıf (Scopus)

Özet

The new complexes [M₂(CO)₁₀(μ-R₂P(S)P(S)R₂)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R₂P(S)P(S)R₂ (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and ³¹P-[¹H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1843-1851
Sayfa sayısı	9
Dergi	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Hacim	31
Basın numarası	10
DOI'lar	https://doi.org/10.1081/SIM-100108266
Yayın durumu	Yayınlandı - 2001
Harici olarak yayınlandı	Evet

Finansman

We thank BP (Turkey) for the provision of the photochemical apparatus. We are grateful to Dr. I. Topaloglu for obtaining the mass spectra at the University of Bristol. We thank the British Council (The Foreign and Commonwealth Office Scholarships) for financial support to Ozan Sanlı S¸ entürk and Fadime Ugˇ ur (Sarikahya). We are grateftul to Mr. P. Heath for obtaining the NMR data at the University of Reading.

Finansörler
British Council

Belgeye Erişim

10.1081/SIM-100108266

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{96a612ee96734e9184304ab015993c6e,

title = "Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)",

abstract = "The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.",

author = "{\c S}ent{\"u}rk, \{Ozan Sanlı\} and Fadime Ugˇur",

year = "2001",

doi = "10.1081/SIM-100108266",

language = "English",

volume = "31",

pages = "1843--1851",

journal = "Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry",

issn = "0094-5714",

number = "10",

}

TY - JOUR

T1 - Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

AU - Şentürk, Ozan Sanlı

AU - Ugˇur, Fadime

PY - 2001

Y1 - 2001

N2 - The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

AB - The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

UR - https://www.scopus.com/pages/publications/0035565366

U2 - 10.1081/SIM-100108266

DO - 10.1081/SIM-100108266

M3 - Article

AN - SCOPUS:0035565366

SN - 0094-5714

VL - 31

SP - 1843

EP - 1851

JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 10

ER -