Özet
The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.
Orijinal dil | İngilizce |
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Sayfa (başlangıç-bitiş) | 1843-1851 |
Sayfa sayısı | 9 |
Dergi | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry |
Hacim | 31 |
Basın numarası | 10 |
DOI'lar | |
Yayın durumu | Yayınlandı - 2001 |
Harici olarak yayınlandı | Evet |
Finansman
We thank BP (Turkey) for the provision of the photochemical apparatus. We are grateful to Dr. I. Topaloglu for obtaining the mass spectra at the University of Bristol. We thank the British Council (The Foreign and Commonwealth Office Scholarships) for financial support to Ozan Sanlı S¸ entürk and Fadime Ugˇ ur (Sarikahya). We are grateftul to Mr. P. Heath for obtaining the NMR data at the University of Reading.
Finansörler | Finansör numarası |
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British Council |