Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)

Ozan Sanlı Şentürk, Fadime Ugˇur

Araştırma sonucu: ???type-name???Makalebilirkişi

30 Atıf (Scopus)

Özet

The new complexes [M2(CO)10(μ-R2P(S)P(S)R2)] (M=Mo, W; R=Me, Et, n-Pr, n-Bu), (la)7(1d) and (2a)7(2d) [(1a), M=Mo, R=Me; (1b), M=Mo, R=Et; (1c), M=Mo, R=n-Pr; (1d), M=Mo, R=n-Bu; (2a), M=W, R=Me; (2b), M=W, R=Et; (2c), M=W, R=n-Pr; (2d), M=W, R=n-Bu] have been prepared by the photochemical reaction of M(CO)6 with R2P(S)P(S)R2 (R=Me, Et, n-Pr, n-Bu). The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H]-NMR spectroscopy and FAB-mass spectrometry. The spectroscopic studies suggest cis-bridging bidentate coordination of the ligand between the two metals.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)1843-1851
Sayfa sayısı9
DergiSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Hacim31
Basın numarası10
DOI'lar
Yayın durumuYayınlandı - 2001
Harici olarak yayınlandıEvet

Finansman

We thank BP (Turkey) for the provision of the photochemical apparatus. We are grateful to Dr. I. Topaloglu for obtaining the mass spectra at the University of Bristol. We thank the British Council (The Foreign and Commonwealth Office Scholarships) for financial support to Ozan Sanlı S¸ entürk and Fadime Ugˇ ur (Sarikahya). We are grateftul to Mr. P. Heath for obtaining the NMR data at the University of Reading.

FinansörlerFinansör numarası
British Council

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    Photochemical synthesis of metal carbonyl complexes of tetraalkyldiphosphine disulfides, [M2(CO)10(μ-R2P(S)P(S)R2)] (M = Mo, W; R = Me, Et, n-Pr, n-Bu)' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

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