Photochemical reactions of Re(CO)5Br with Ph2P(S) (CH2)nP(S)Ph2 (n = 1,2,3)

Elif Subasi; Ozan Sanli Sentürk; Fadime Ugur

doi:10.1515/znb-2004-0715

Photochemical reactions of Re(CO)₅Br with Ph₂P(S) (CH₂)_nP(S)Ph₂ (n = 1,2,3)

Elif Subasi, Ozan Sanli Sentürk^*, Fadime Ugur

^*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

17 Atıf (Scopus)

Özet

The complexes fac-[Re(CO)₃Br{Ph₂P(S)(CH ₂)nP(S)Ph₂}] [1a, n = 1; 2a, n = 2; 3a, n = 3] and [Re₂(CO)₈Br₂{μ-Ph₂P(S)(CH ₂)_nP(S)Ph₂}] [1b, n = 1; 2b, n = 2; 3b, n = 3] have been prepared by the photochemical reaction of Re(CO)₅Br with Ph₂P(S)(CH₂)_nP(S)Ph₂. The products have been characterized by elemental analysis, mass spectroscopy, FT-IR and ³¹ P-[¹H]-NMR spectrometry. The results suggest cis-chelate bidentate coordination of the ligand in fac-1a-3a and cis-bridging bidentate coordination of the ligand between two metals in 1b-3b.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	836-838
Sayfa sayısı	3
Dergi	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Hacim	59
Basın numarası	7
DOI'lar	https://doi.org/10.1515/znb-2004-0715
Yayın durumu	Yayınlandı - Tem 2004
Harici olarak yayınlandı	Evet

Finansman

We thank BP (Turkey) for the provision of the photochemical apparatus and Research Foundation of Ege University for funds. We thank TUBITAK for allocation of time at the NMR, mass spectrometer and for elemental analyses.

Finansörler	Finansör numarası
BP
Ege University Research Foundation

Belgeye Erişim

10.1515/znb-2004-0715

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{b00cc22da89b4a499a596cbd474c15a6,

title = "Photochemical reactions of Re(CO)5Br with Ph2P(S) (CH2)nP(S)Ph2 (n = 1,2,3)",

abstract = "The complexes fac-[Re(CO)3Br{Ph2P(S)(CH 2)nP(S)Ph2}] [1a, n = 1; 2a, n = 2; 3a, n = 3] and [Re2(CO)8Br2{μ-Ph2P(S)(CH 2)nP(S)Ph2}] [1b, n = 1; 2b, n = 2; 3b, n = 3] have been prepared by the photochemical reaction of Re(CO)5Br with Ph2P(S)(CH2)nP(S)Ph2. The products have been characterized by elemental analysis, mass spectroscopy, FT-IR and 31 P-[1H]-NMR spectrometry. The results suggest cis-chelate bidentate coordination of the ligand in fac-1a-3a and cis-bridging bidentate coordination of the ligand between two metals in 1b-3b.",

keywords = "Diphosphines, Metal Carbonyls",

author = "Elif Subasi and Sent{\"u}rk, {Ozan Sanli} and Fadime Ugur",

year = "2004",

month = jul,

doi = "10.1515/znb-2004-0715",

language = "English",

volume = "59",

pages = "836--838",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "7",

}

TY - JOUR

T1 - Photochemical reactions of Re(CO)5Br with Ph2P(S) (CH2)nP(S)Ph2 (n = 1,2,3)

AU - Subasi, Elif

AU - Sentürk, Ozan Sanli

AU - Ugur, Fadime

PY - 2004/7

Y1 - 2004/7

N2 - The complexes fac-[Re(CO)3Br{Ph2P(S)(CH 2)nP(S)Ph2}] [1a, n = 1; 2a, n = 2; 3a, n = 3] and [Re2(CO)8Br2{μ-Ph2P(S)(CH 2)nP(S)Ph2}] [1b, n = 1; 2b, n = 2; 3b, n = 3] have been prepared by the photochemical reaction of Re(CO)5Br with Ph2P(S)(CH2)nP(S)Ph2. The products have been characterized by elemental analysis, mass spectroscopy, FT-IR and 31 P-[1H]-NMR spectrometry. The results suggest cis-chelate bidentate coordination of the ligand in fac-1a-3a and cis-bridging bidentate coordination of the ligand between two metals in 1b-3b.

AB - The complexes fac-[Re(CO)3Br{Ph2P(S)(CH 2)nP(S)Ph2}] [1a, n = 1; 2a, n = 2; 3a, n = 3] and [Re2(CO)8Br2{μ-Ph2P(S)(CH 2)nP(S)Ph2}] [1b, n = 1; 2b, n = 2; 3b, n = 3] have been prepared by the photochemical reaction of Re(CO)5Br with Ph2P(S)(CH2)nP(S)Ph2. The products have been characterized by elemental analysis, mass spectroscopy, FT-IR and 31 P-[1H]-NMR spectrometry. The results suggest cis-chelate bidentate coordination of the ligand in fac-1a-3a and cis-bridging bidentate coordination of the ligand between two metals in 1b-3b.

KW - Diphosphines

KW - Metal Carbonyls

UR - http://www.scopus.com/inward/record.url?scp=4243052638&partnerID=8YFLogxK

U2 - 10.1515/znb-2004-0715

DO - 10.1515/znb-2004-0715

M3 - Article

AN - SCOPUS:4243052638

SN - 0932-0776

VL - 59

SP - 836

EP - 838

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 7

ER -